catena-Poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N)nickel(II)]-μ-oxido-[dioxidotungstate(VI)]-μ-oxido] tetra­hydrate]

In the title compound, {[NiWO(4)(C(16)H(36)N(4))]·4H(2)O}(n), the Ni(II) ion lies on an inversion center and is octahedrally coordinated by four N atoms of the tetradentate macrocyclic 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane (L) ligand in the equatorial plane and two O atoms...

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Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Yuan, Xian-You, Li, Zhi-Zhang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435596/
https://www.ncbi.nlm.nih.gov/pubmed/22969469
http://dx.doi.org/10.1107/S1600536812034538
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author Ou, Guang-Chuan
Yuan, Xian-You
Li, Zhi-Zhang
author_facet Ou, Guang-Chuan
Yuan, Xian-You
Li, Zhi-Zhang
author_sort Ou, Guang-Chuan
collection PubMed
description In the title compound, {[NiWO(4)(C(16)H(36)N(4))]·4H(2)O}(n), the Ni(II) ion lies on an inversion center and is octahedrally coordinated by four N atoms of the tetradentate macrocyclic 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane (L) ligand in the equatorial plane and two O atoms of [WO(4)](2−) anions in axial positions. Each [WO(4)](2−) anion bridges two adjacent [NiL](2+) cations, forming a chain along [001]. The chains are further connected via N—H⋯O, O—H⋯O and C—H⋯O hydrogen-bonding inter­actions, generating a three-dimensional structure.
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spelling pubmed-34355962012-09-11 catena-Poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N)nickel(II)]-μ-oxido-[dioxidotungstate(VI)]-μ-oxido] tetra­hydrate] Ou, Guang-Chuan Yuan, Xian-You Li, Zhi-Zhang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[NiWO(4)(C(16)H(36)N(4))]·4H(2)O}(n), the Ni(II) ion lies on an inversion center and is octahedrally coordinated by four N atoms of the tetradentate macrocyclic 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane (L) ligand in the equatorial plane and two O atoms of [WO(4)](2−) anions in axial positions. Each [WO(4)](2−) anion bridges two adjacent [NiL](2+) cations, forming a chain along [001]. The chains are further connected via N—H⋯O, O—H⋯O and C—H⋯O hydrogen-bonding inter­actions, generating a three-dimensional structure. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435596/ /pubmed/22969469 http://dx.doi.org/10.1107/S1600536812034538 Text en © Ou et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ou, Guang-Chuan
Yuan, Xian-You
Li, Zhi-Zhang
catena-Poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N)nickel(II)]-μ-oxido-[dioxidotungstate(VI)]-μ-oxido] tetra­hydrate]
title catena-Poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N)nickel(II)]-μ-oxido-[dioxidotungstate(VI)]-μ-oxido] tetra­hydrate]
title_full catena-Poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N)nickel(II)]-μ-oxido-[dioxidotungstate(VI)]-μ-oxido] tetra­hydrate]
title_fullStr catena-Poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N)nickel(II)]-μ-oxido-[dioxidotungstate(VI)]-μ-oxido] tetra­hydrate]
title_full_unstemmed catena-Poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N)nickel(II)]-μ-oxido-[dioxidotungstate(VI)]-μ-oxido] tetra­hydrate]
title_short catena-Poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N)nickel(II)]-μ-oxido-[dioxidotungstate(VI)]-μ-oxido] tetra­hydrate]
title_sort catena-poly[[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) n)nickel(ii)]-μ-oxido-[dioxidotungstate(vi)]-μ-oxido] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435596/
https://www.ncbi.nlm.nih.gov/pubmed/22969469
http://dx.doi.org/10.1107/S1600536812034538
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