Cargando…
catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2) N (1),O}copper(II)]-μ-dicyanamido-κ(2) N (1):N (5)] monohydrate]
The Cu(II) atoms in the title coordination polymer, {[Cu(C(13)H(11)N(4)O)(C(2)N(3))]·H(2)O}(n), are N,N′,O-chelated by the deprotonated Schiff base ligands, and adjacent metal atoms are bridged by the dicyanamide ions, generating a polymeric chain that propagates along the b axis. The two independen...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435598/ https://www.ncbi.nlm.nih.gov/pubmed/22969471 http://dx.doi.org/10.1107/S1600536812035283 |
| _version_ | 1782242548610236416 |
|---|---|
| author | Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng |
| author_facet | Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng |
| author_sort | Kunnath, Roji J. |
| collection | PubMed |
| description | The Cu(II) atoms in the title coordination polymer, {[Cu(C(13)H(11)N(4)O)(C(2)N(3))]·H(2)O}(n), are N,N′,O-chelated by the deprotonated Schiff base ligands, and adjacent metal atoms are bridged by the dicyanamide ions, generating a polymeric chain that propagates along the b axis. The two independent metal atoms show a square-pyramidal N(4)O coordination. The two independent water molecules are disordered over two positions; each water molecule is a hydrogen-bond donor to a carbonyl O atom. Weak N—H⋯N hydrogen bonding is also observed. |
| format | Online Article Text |
| id | pubmed-3435598 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34355982012-09-11 catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2) N (1),O}copper(II)]-μ-dicyanamido-κ(2) N (1):N (5)] monohydrate] Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atoms in the title coordination polymer, {[Cu(C(13)H(11)N(4)O)(C(2)N(3))]·H(2)O}(n), are N,N′,O-chelated by the deprotonated Schiff base ligands, and adjacent metal atoms are bridged by the dicyanamide ions, generating a polymeric chain that propagates along the b axis. The two independent metal atoms show a square-pyramidal N(4)O coordination. The two independent water molecules are disordered over two positions; each water molecule is a hydrogen-bond donor to a carbonyl O atom. Weak N—H⋯N hydrogen bonding is also observed. International Union of Crystallography 2012-08-15 /pmc/articles/PMC3435598/ /pubmed/22969471 http://dx.doi.org/10.1107/S1600536812035283 Text en © Kunnath et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2) N (1),O}copper(II)]-μ-dicyanamido-κ(2) N (1):N (5)] monohydrate] |
| title |
catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II)]-μ-dicyanamido-κ(2)
N
(1):N
(5)] monohydrate] |
| title_full |
catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II)]-μ-dicyanamido-κ(2)
N
(1):N
(5)] monohydrate] |
| title_fullStr |
catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II)]-μ-dicyanamido-κ(2)
N
(1):N
(5)] monohydrate] |
| title_full_unstemmed |
catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II)]-μ-dicyanamido-κ(2)
N
(1):N
(5)] monohydrate] |
| title_short |
catena-Poly[[[{1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II)]-μ-dicyanamido-κ(2)
N
(1):N
(5)] monohydrate] |
| title_sort | catena-poly[[[{1-[(e)-phenyl(pyridin-2-yl-κn)methylidene]semicarbazidato-κ(2)
n
(1),o}copper(ii)]-μ-dicyanamido-κ(2)
n
(1):n
(5)] monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435598/ https://www.ncbi.nlm.nih.gov/pubmed/22969471 http://dx.doi.org/10.1107/S1600536812035283 |
| work_keys_str_mv | AT kunnathrojij catenapoly1ephenylpyridin2ylknmethylidenesemicarbazidatok2n1ocopperiimdicyanamidok2n1n5monohydrate AT prathapachandrakurupmr catenapoly1ephenylpyridin2ylknmethylidenesemicarbazidatok2n1ocopperiimdicyanamidok2n1n5monohydrate AT ngseikweng catenapoly1ephenylpyridin2ylknmethylidenesemicarbazidatok2n1ocopperiimdicyanamidok2n1n5monohydrate |