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Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2) O (1):O (1′)]magnesium] 0.4-hydrate]
In the title compound, {[Mg(C(8)H(6)FO(3))(2)(H(2)O)(2)]·0.4H(2)O}(n), slightly distorted octahedral MgO(6) complex units have crystallographic inversion symmetry, the coordination polyhedron comprising two trans-related water molecules and four carboxyl O-atom donors, two of which are bridging. W...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435600/ https://www.ncbi.nlm.nih.gov/pubmed/22969473 http://dx.doi.org/10.1107/S1600536812035246 |
| _version_ | 1782242549093629952 |
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| author | Smith, Graham |
| author_facet | Smith, Graham |
| author_sort | Smith, Graham |
| collection | PubMed |
| description | In the title compound, {[Mg(C(8)H(6)FO(3))(2)(H(2)O)(2)]·0.4H(2)O}(n), slightly distorted octahedral MgO(6) complex units have crystallographic inversion symmetry, the coordination polyhedron comprising two trans-related water molecules and four carboxyl O-atom donors, two of which are bridging. Within the two-dimensional complex polymer which is parallel to (100), coordinating water molecules form intermolecular O—H⋯O hydrogen bonds with carboxylate and phenoxy O-atom acceptors, as well as with the partial-occupancy solvent water molecules. |
| format | Online Article Text |
| id | pubmed-3435600 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34356002012-09-11 Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2) O (1):O (1′)]magnesium] 0.4-hydrate] Smith, Graham Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mg(C(8)H(6)FO(3))(2)(H(2)O)(2)]·0.4H(2)O}(n), slightly distorted octahedral MgO(6) complex units have crystallographic inversion symmetry, the coordination polyhedron comprising two trans-related water molecules and four carboxyl O-atom donors, two of which are bridging. Within the two-dimensional complex polymer which is parallel to (100), coordinating water molecules form intermolecular O—H⋯O hydrogen bonds with carboxylate and phenoxy O-atom acceptors, as well as with the partial-occupancy solvent water molecules. International Union of Crystallography 2012-08-15 /pmc/articles/PMC3435600/ /pubmed/22969473 http://dx.doi.org/10.1107/S1600536812035246 Text en © Graham Smith 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Smith, Graham Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2) O (1):O (1′)]magnesium] 0.4-hydrate] |
| title | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2)
O
(1):O
(1′)]magnesium] 0.4-hydrate] |
| title_full | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2)
O
(1):O
(1′)]magnesium] 0.4-hydrate] |
| title_fullStr | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2)
O
(1):O
(1′)]magnesium] 0.4-hydrate] |
| title_full_unstemmed | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2)
O
(1):O
(1′)]magnesium] 0.4-hydrate] |
| title_short | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2)
O
(1):O
(1′)]magnesium] 0.4-hydrate] |
| title_sort | poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ(2)
o
(1):o
(1′)]magnesium] 0.4-hydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435600/ https://www.ncbi.nlm.nih.gov/pubmed/22969473 http://dx.doi.org/10.1107/S1600536812035246 |
| work_keys_str_mv | AT smithgraham polydiaquabism24fluorophenoxyacetatok2o1o1magnesium04hydrate |