Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc

The title mononuclear Zn(II) complex, [ZnCl(2)(C(15)H(13)N(5))(2)], is isotypic with the previously reported Hg(II) complex. The Zn(II) atom is located on a twofold rotation axis and has a distorted tetra­hedral environment of two Cl atoms and two N atoms from two heterocyclic ligands. In the crysta...

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Detalles Bibliográficos
Autores principales: Song, Lianqing, Zhao, Meihong, Cui, Guoshi, Gao, Jianghua, Lin, Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435601/
https://www.ncbi.nlm.nih.gov/pubmed/22969474
http://dx.doi.org/10.1107/S160053681203526X
Descripción
Sumario:The title mononuclear Zn(II) complex, [ZnCl(2)(C(15)H(13)N(5))(2)], is isotypic with the previously reported Hg(II) complex. The Zn(II) atom is located on a twofold rotation axis and has a distorted tetra­hedral environment of two Cl atoms and two N atoms from two heterocyclic ligands. In the crystal, complex mol­ecules are extended by inter­molecular π–π inter­actions [centroid–centroid distance = 3.792 (2) Å] into a three-dimensional supra­molecular network.

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