Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc

The title mononuclear Zn(II) complex, [ZnCl(2)(C(15)H(13)N(5))(2)], is isotypic with the previously reported Hg(II) complex. The Zn(II) atom is located on a twofold rotation axis and has a distorted tetra­hedral environment of two Cl atoms and two N atoms from two heterocyclic ligands. In the crysta...

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Detalles Bibliográficos
Autores principales: Song, Lianqing, Zhao, Meihong, Cui, Guoshi, Gao, Jianghua, Lin, Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435601/
https://www.ncbi.nlm.nih.gov/pubmed/22969474
http://dx.doi.org/10.1107/S160053681203526X
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author Song, Lianqing
Zhao, Meihong
Cui, Guoshi
Gao, Jianghua
Lin, Lin
author_facet Song, Lianqing
Zhao, Meihong
Cui, Guoshi
Gao, Jianghua
Lin, Lin
author_sort Song, Lianqing
collection PubMed
description The title mononuclear Zn(II) complex, [ZnCl(2)(C(15)H(13)N(5))(2)], is isotypic with the previously reported Hg(II) complex. The Zn(II) atom is located on a twofold rotation axis and has a distorted tetra­hedral environment of two Cl atoms and two N atoms from two heterocyclic ligands. In the crystal, complex mol­ecules are extended by inter­molecular π–π inter­actions [centroid–centroid distance = 3.792 (2) Å] into a three-dimensional supra­molecular network.
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spelling pubmed-34356012012-09-11 Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc Song, Lianqing Zhao, Meihong Cui, Guoshi Gao, Jianghua Lin, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear Zn(II) complex, [ZnCl(2)(C(15)H(13)N(5))(2)], is isotypic with the previously reported Hg(II) complex. The Zn(II) atom is located on a twofold rotation axis and has a distorted tetra­hedral environment of two Cl atoms and two N atoms from two heterocyclic ligands. In the crystal, complex mol­ecules are extended by inter­molecular π–π inter­actions [centroid–centroid distance = 3.792 (2) Å] into a three-dimensional supra­molecular network. International Union of Crystallography 2012-08-15 /pmc/articles/PMC3435601/ /pubmed/22969474 http://dx.doi.org/10.1107/S160053681203526X Text en © Song et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Lianqing
Zhao, Meihong
Cui, Guoshi
Gao, Jianghua
Lin, Lin
Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc
title Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc
title_full Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc
title_fullStr Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc
title_full_unstemmed Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc
title_short Dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κN (3))meth­yl]benzotriazole}zinc
title_sort dichloridobis{1-[(2-methyl­benzimidazol-1-yl-κn (3))meth­yl]benzotriazole}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435601/
https://www.ncbi.nlm.nih.gov/pubmed/22969474
http://dx.doi.org/10.1107/S160053681203526X
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