Cargando…

(Cyanato-κN){1-[(E)-phen­yl(pyridin-2-yl-κN)methyl­idene]semicarbazidato-κ(2) N (1),O}copper(II)

The Cu(II) atom in the title compound, [Cu(C(13)H(11)N(4)O)(NCO)], is N,N′,O-chelated by the mono-deprotonated Schiff base ligand and it is also covalently bonded to the nitro­gen end of the cyanate ion. The Cu(II) atom shows a square-planar coordination that is distorted towards square-pyramidal ow...

Descripción completa

Detalles Bibliográficos
Autores principales: Kunnath, Roji J., Prathapachandra Kurup, M.R., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435602/
https://www.ncbi.nlm.nih.gov/pubmed/22969475
http://dx.doi.org/10.1107/S1600536812035386
_version_ 1782242549559197696
author Kunnath, Roji J.
Prathapachandra Kurup, M.R.
Ng, Seik Weng
author_facet Kunnath, Roji J.
Prathapachandra Kurup, M.R.
Ng, Seik Weng
author_sort Kunnath, Roji J.
collection PubMed
description The Cu(II) atom in the title compound, [Cu(C(13)H(11)N(4)O)(NCO)], is N,N′,O-chelated by the mono-deprotonated Schiff base ligand and it is also covalently bonded to the nitro­gen end of the cyanate ion. The Cu(II) atom shows a square-planar coordination that is distorted towards square-pyramidal owing to an inter­molecular Cu⋯N(cyanate) inter­action [2.623 (2) Å], which gives a centrosymmetric dimer. In the square-planar description, the Cu(II) atom is displaced out of the square plane [r.m.s. deviation = 0.048 Å] by 0.084 (1) Å in the direction of the apical occupant. In the crystal, adjacent complex dimers are linked by an amine N—H⋯N hydrogen-bond pair, also giving a centrosymmetric cyclic association [graph set R (2) (2)(8)], generating a linear chain parallel to [110].
format Online
Article
Text
id pubmed-3435602
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34356022012-09-11 (Cyanato-κN){1-[(E)-phen­yl(pyridin-2-yl-κN)methyl­idene]semicarbazidato-κ(2) N (1),O}copper(II) Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [Cu(C(13)H(11)N(4)O)(NCO)], is N,N′,O-chelated by the mono-deprotonated Schiff base ligand and it is also covalently bonded to the nitro­gen end of the cyanate ion. The Cu(II) atom shows a square-planar coordination that is distorted towards square-pyramidal owing to an inter­molecular Cu⋯N(cyanate) inter­action [2.623 (2) Å], which gives a centrosymmetric dimer. In the square-planar description, the Cu(II) atom is displaced out of the square plane [r.m.s. deviation = 0.048 Å] by 0.084 (1) Å in the direction of the apical occupant. In the crystal, adjacent complex dimers are linked by an amine N—H⋯N hydrogen-bond pair, also giving a centrosymmetric cyclic association [graph set R (2) (2)(8)], generating a linear chain parallel to [110]. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435602/ /pubmed/22969475 http://dx.doi.org/10.1107/S1600536812035386 Text en © Kunnath et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kunnath, Roji J.
Prathapachandra Kurup, M.R.
Ng, Seik Weng
(Cyanato-κN){1-[(E)-phen­yl(pyridin-2-yl-κN)methyl­idene]semicarbazidato-κ(2) N (1),O}copper(II)
title (Cyanato-κN){1-[(E)-phen­yl(pyridin-2-yl-κN)methyl­idene]semicarbazidato-κ(2) N (1),O}copper(II)
title_full (Cyanato-κN){1-[(E)-phen­yl(pyridin-2-yl-κN)methyl­idene]semicarbazidato-κ(2) N (1),O}copper(II)
title_fullStr (Cyanato-κN){1-[(E)-phen­yl(pyridin-2-yl-κN)methyl­idene]semicarbazidato-κ(2) N (1),O}copper(II)
title_full_unstemmed (Cyanato-κN){1-[(E)-phen­yl(pyridin-2-yl-κN)methyl­idene]semicarbazidato-κ(2) N (1),O}copper(II)
title_short (Cyanato-κN){1-[(E)-phen­yl(pyridin-2-yl-κN)methyl­idene]semicarbazidato-κ(2) N (1),O}copper(II)
title_sort (cyanato-κn){1-[(e)-phen­yl(pyridin-2-yl-κn)methyl­idene]semicarbazidato-κ(2) n (1),o}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435602/
https://www.ncbi.nlm.nih.gov/pubmed/22969475
http://dx.doi.org/10.1107/S1600536812035386
work_keys_str_mv AT kunnathrojij cyanatokn1ephenylpyridin2ylknmethylidenesemicarbazidatok2n1ocopperii
AT prathapachandrakurupmr cyanatokn1ephenylpyridin2ylknmethylidenesemicarbazidatok2n1ocopperii
AT ngseikweng cyanatokn1ephenylpyridin2ylknmethylidenesemicarbazidatok2n1ocopperii