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(Cyanato-κN){1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2) N (1),O}copper(II)
The Cu(II) atom in the title compound, [Cu(C(13)H(11)N(4)O)(NCO)], is N,N′,O-chelated by the mono-deprotonated Schiff base ligand and it is also covalently bonded to the nitrogen end of the cyanate ion. The Cu(II) atom shows a square-planar coordination that is distorted towards square-pyramidal ow...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435602/ https://www.ncbi.nlm.nih.gov/pubmed/22969475 http://dx.doi.org/10.1107/S1600536812035386 |
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author | Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng |
author_facet | Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng |
author_sort | Kunnath, Roji J. |
collection | PubMed |
description | The Cu(II) atom in the title compound, [Cu(C(13)H(11)N(4)O)(NCO)], is N,N′,O-chelated by the mono-deprotonated Schiff base ligand and it is also covalently bonded to the nitrogen end of the cyanate ion. The Cu(II) atom shows a square-planar coordination that is distorted towards square-pyramidal owing to an intermolecular Cu⋯N(cyanate) interaction [2.623 (2) Å], which gives a centrosymmetric dimer. In the square-planar description, the Cu(II) atom is displaced out of the square plane [r.m.s. deviation = 0.048 Å] by 0.084 (1) Å in the direction of the apical occupant. In the crystal, adjacent complex dimers are linked by an amine N—H⋯N hydrogen-bond pair, also giving a centrosymmetric cyclic association [graph set R (2) (2)(8)], generating a linear chain parallel to [110]. |
format | Online Article Text |
id | pubmed-3435602 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34356022012-09-11 (Cyanato-κN){1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2) N (1),O}copper(II) Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [Cu(C(13)H(11)N(4)O)(NCO)], is N,N′,O-chelated by the mono-deprotonated Schiff base ligand and it is also covalently bonded to the nitrogen end of the cyanate ion. The Cu(II) atom shows a square-planar coordination that is distorted towards square-pyramidal owing to an intermolecular Cu⋯N(cyanate) interaction [2.623 (2) Å], which gives a centrosymmetric dimer. In the square-planar description, the Cu(II) atom is displaced out of the square plane [r.m.s. deviation = 0.048 Å] by 0.084 (1) Å in the direction of the apical occupant. In the crystal, adjacent complex dimers are linked by an amine N—H⋯N hydrogen-bond pair, also giving a centrosymmetric cyclic association [graph set R (2) (2)(8)], generating a linear chain parallel to [110]. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435602/ /pubmed/22969475 http://dx.doi.org/10.1107/S1600536812035386 Text en © Kunnath et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng (Cyanato-κN){1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2) N (1),O}copper(II) |
title | (Cyanato-κN){1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II) |
title_full | (Cyanato-κN){1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II) |
title_fullStr | (Cyanato-κN){1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II) |
title_full_unstemmed | (Cyanato-κN){1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II) |
title_short | (Cyanato-κN){1-[(E)-phenyl(pyridin-2-yl-κN)methylidene]semicarbazidato-κ(2)
N
(1),O}copper(II) |
title_sort | (cyanato-κn){1-[(e)-phenyl(pyridin-2-yl-κn)methylidene]semicarbazidato-κ(2)
n
(1),o}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435602/ https://www.ncbi.nlm.nih.gov/pubmed/22969475 http://dx.doi.org/10.1107/S1600536812035386 |
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