Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate

The Cu(II) atom in the title compound, [CuCl(2)(C(16)H(15)N(3)O)]·H(2)O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The api...

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Detalles Bibliográficos
Autores principales: Kunnath, Roji J., Prathapachandra Kurup, M.R., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435603/
https://www.ncbi.nlm.nih.gov/pubmed/22969476
http://dx.doi.org/10.1107/S1600536812035398
Descripción
Sumario:The Cu(II) atom in the title compound, [CuCl(2)(C(16)H(15)N(3)O)]·H(2)O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water mol­ecules, the inter­action generating a centrosymmetric dimer through a cyclic R (4) (2)(8) association.

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