Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate

The Cu(II) atom in the title compound, [CuCl(2)(C(16)H(15)N(3)O)]·H(2)O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The api...

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Detalles Bibliográficos
Autores principales: Kunnath, Roji J., Prathapachandra Kurup, M.R., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435603/
https://www.ncbi.nlm.nih.gov/pubmed/22969476
http://dx.doi.org/10.1107/S1600536812035398
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author Kunnath, Roji J.
Prathapachandra Kurup, M.R.
Ng, Seik Weng
author_facet Kunnath, Roji J.
Prathapachandra Kurup, M.R.
Ng, Seik Weng
author_sort Kunnath, Roji J.
collection PubMed
description The Cu(II) atom in the title compound, [CuCl(2)(C(16)H(15)N(3)O)]·H(2)O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water mol­ecules, the inter­action generating a centrosymmetric dimer through a cyclic R (4) (2)(8) association.
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spelling pubmed-34356032012-09-11 Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate Kunnath, Roji J. Prathapachandra Kurup, M.R. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [CuCl(2)(C(16)H(15)N(3)O)]·H(2)O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water mol­ecules, the inter­action generating a centrosymmetric dimer through a cyclic R (4) (2)(8) association. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435603/ /pubmed/22969476 http://dx.doi.org/10.1107/S1600536812035398 Text en © Kunnath et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kunnath, Roji J.
Prathapachandra Kurup, M.R.
Ng, Seik Weng
Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate
title Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate
title_full Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate
title_fullStr Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate
title_full_unstemmed Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate
title_short Dichlorido(1-{(E)-[phen­yl(pyridin-2-yl-κN)methyl­idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate
title_sort dichlorido(1-{(e)-[phen­yl(pyridin-2-yl-κn)methyl­idene]amino-κn}pyrrolidin-2-one-κo)copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435603/
https://www.ncbi.nlm.nih.gov/pubmed/22969476
http://dx.doi.org/10.1107/S1600536812035398
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AT ngseikweng dichlorido1ephenylpyridin2ylknmethylideneaminoknpyrrolidin2onekocopperiimonohydrate

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