Diaqua­bis­{3-[4-(1H-imidazol-1-yl)phenyl]-5-(pyridin-2-yl-κN)-1H-1,2,4-triazol-1-ido-κN (1)}zinc

The centrosymmetric mol­ecule of the title compound, [Zn(C(16)H(11)N(6))(2)(H(2)O)(2)], contains one Zn(2+) ion located on a center of symmetry, two 3-[4-(1H-imidazol-1-yl)phen­yl]-5-(pyridin-2-yl)-1H-1,2,4-triazol-1-ide (Ippyt) ligands and two coordinating water mol­ecules. The Zn(II) ion is six-co...

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Detalles Bibliográficos
Autores principales: Wang, You-Song, Qiu, Guang-Mei, Wang, Cui-Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435604/
https://www.ncbi.nlm.nih.gov/pubmed/22969477
http://dx.doi.org/10.1107/S1600536812035428
Descripción
Sumario:The centrosymmetric mol­ecule of the title compound, [Zn(C(16)H(11)N(6))(2)(H(2)O)(2)], contains one Zn(2+) ion located on a center of symmetry, two 3-[4-(1H-imidazol-1-yl)phen­yl]-5-(pyridin-2-yl)-1H-1,2,4-triazol-1-ide (Ippyt) ligands and two coordinating water mol­ecules. The Zn(II) ion is six-coordinated in a distorted octa­hedral coordination geometry by four N atoms from two Ippyt ligands and by two O atoms from two water mol­ecules. Adjacent units are inter­connected though O—H⋯N hydrogen bonds, forming a three-dimensional network.

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