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Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate
In the title compound, [Ir(C(18)H(15)P)(2)(CO)(3)]PF(6)·CH(3)OH, the Ir(I) atom is coordinated by two triphenylphosphine ligands in axial sites and three carbonyl ligands in the equatorial plane of a fairly regular trigonal bipyramid: the equatorial C—Ir—C angles range from 115.45 (9) to 126.42 (10...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435607/ https://www.ncbi.nlm.nih.gov/pubmed/22969480 http://dx.doi.org/10.1107/S1600536812035593 |
| _version_ | 1782242550741991424 |
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| author | Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas |
| author_facet | Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas |
| author_sort | Engelbrecht, Ilana |
| collection | PubMed |
| description | In the title compound, [Ir(C(18)H(15)P)(2)(CO)(3)]PF(6)·CH(3)OH, the Ir(I) atom is coordinated by two triphenylphosphine ligands in axial sites and three carbonyl ligands in the equatorial plane of a fairly regular trigonal bipyramid: the equatorial C—Ir—C angles range from 115.45 (9) to 126.42 (10)°. The small deviations from the ideal tetrahedral geometry around the P atoms are illustrated by C—P—C angles ranging from 104.08 (9) to 106.46 (9)°. In the crystal, the molecules are linked by weak C—H⋯F, C—H⋯O and C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3435607 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34356072012-09-11 Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(18)H(15)P)(2)(CO)(3)]PF(6)·CH(3)OH, the Ir(I) atom is coordinated by two triphenylphosphine ligands in axial sites and three carbonyl ligands in the equatorial plane of a fairly regular trigonal bipyramid: the equatorial C—Ir—C angles range from 115.45 (9) to 126.42 (10)°. The small deviations from the ideal tetrahedral geometry around the P atoms are illustrated by C—P—C angles ranging from 104.08 (9) to 106.46 (9)°. In the crystal, the molecules are linked by weak C—H⋯F, C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435607/ /pubmed/22969480 http://dx.doi.org/10.1107/S1600536812035593 Text en © Engelbrecht et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate |
| title | Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate |
| title_full | Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate |
| title_fullStr | Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate |
| title_full_unstemmed | Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate |
| title_short | Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate |
| title_sort | tricarbonylbis(triphenylphosphane-κp)iridium(i) hexafluoridophosphate methanol monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435607/ https://www.ncbi.nlm.nih.gov/pubmed/22969480 http://dx.doi.org/10.1107/S1600536812035593 |
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