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Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate
In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octahedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a methanol molecule and three Cl atoms. In the crystal, intermolecular O—...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435608/ https://www.ncbi.nlm.nih.gov/pubmed/22969481 http://dx.doi.org/10.1107/S1600536812035490 |
Sumario: | In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octahedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a methanol molecule and three Cl atoms. In the crystal, intermolecular O—H⋯O and O—H⋯Cl hydrogen bonds link the complex and solvent methanol molecules. Intramolecular C—H⋯Cl hydrogen bonds are also present in the complex. |
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