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Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate

In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a methanol mol­ecule and three Cl atoms. In the crystal, inter­molecular O—...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435608/
https://www.ncbi.nlm.nih.gov/pubmed/22969481
http://dx.doi.org/10.1107/S1600536812035490
Descripción
Sumario:In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a methanol mol­ecule and three Cl atoms. In the crystal, inter­molecular O—H⋯O and O—H⋯Cl hydrogen bonds link the complex and solvent methanol mol­ecules. Intra­molecular C—H⋯Cl hydrogen bonds are also present in the complex.