Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate

In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a methanol mol­ecule and three Cl atoms. In the crystal, inter­molecular O—...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435608/
https://www.ncbi.nlm.nih.gov/pubmed/22969481
http://dx.doi.org/10.1107/S1600536812035490
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_sort Shirvan, Sadif A.
collection PubMed
description In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a methanol mol­ecule and three Cl atoms. In the crystal, inter­molecular O—H⋯O and O—H⋯Cl hydrogen bonds link the complex and solvent methanol mol­ecules. Intra­molecular C—H⋯Cl hydrogen bonds are also present in the complex.
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spelling pubmed-34356082012-09-11 Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a methanol mol­ecule and three Cl atoms. In the crystal, inter­molecular O—H⋯O and O—H⋯Cl hydrogen bonds link the complex and solvent methanol mol­ecules. Intra­molecular C—H⋯Cl hydrogen bonds are also present in the complex. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435608/ /pubmed/22969481 http://dx.doi.org/10.1107/S1600536812035490 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate
title Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate
title_full Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate
title_fullStr Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate
title_full_unstemmed Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate
title_short Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(methanol-κO)indium(III) methanol monosolvate
title_sort trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)(methanol-κo)indium(iii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435608/
https://www.ncbi.nlm.nih.gov/pubmed/22969481
http://dx.doi.org/10.1107/S1600536812035490
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