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[5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)
The title compound, [Ni(C(28)H(28)N(4))], crystallizes with two independent molecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435609/ https://www.ncbi.nlm.nih.gov/pubmed/22969482 http://dx.doi.org/10.1107/S1600536812035726 |
Sumario: | The title compound, [Ni(C(28)H(28)N(4))], crystallizes with two independent molecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for the first molecule and 0.026 Å for the molecule located on an inversion center. The average Ni—N bond lengths are 1.955 (2) and 1.956 (2) Å in the two molecules. The molecules form π–π dimers of intermediary strength with a mean plane separation of 3.36 (2) Å. |
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