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[5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II)

The title compound, [Ni(C(28)H(28)N(4))], crystallizes with two independent mol­ecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for...

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Detalles Bibliográficos
Autor principal: Senge, Mathias O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435609/
https://www.ncbi.nlm.nih.gov/pubmed/22969482
http://dx.doi.org/10.1107/S1600536812035726
Descripción
Sumario:The title compound, [Ni(C(28)H(28)N(4))], crystallizes with two independent mol­ecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for the first mol­ecule and 0.026 Å for the mol­ecule located on an inversion center. The average Ni—N bond lengths are 1.955 (2) and 1.956 (2) Å in the two mol­ecules. The mol­ecules form π–π dimers of inter­mediary strength with a mean plane separation of 3.36 (2) Å.