[5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II)

The title compound, [Ni(C(28)H(28)N(4))], crystallizes with two independent mol­ecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for...

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Autor principal: Senge, Mathias O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435609/
https://www.ncbi.nlm.nih.gov/pubmed/22969482
http://dx.doi.org/10.1107/S1600536812035726
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author Senge, Mathias O.
author_facet Senge, Mathias O.
author_sort Senge, Mathias O.
collection PubMed
description The title compound, [Ni(C(28)H(28)N(4))], crystallizes with two independent mol­ecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for the first mol­ecule and 0.026 Å for the mol­ecule located on an inversion center. The average Ni—N bond lengths are 1.955 (2) and 1.956 (2) Å in the two mol­ecules. The mol­ecules form π–π dimers of inter­mediary strength with a mean plane separation of 3.36 (2) Å.
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spelling pubmed-34356092012-09-11 [5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II) Senge, Mathias O. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(28)H(28)N(4))], crystallizes with two independent mol­ecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for the first mol­ecule and 0.026 Å for the mol­ecule located on an inversion center. The average Ni—N bond lengths are 1.955 (2) and 1.956 (2) Å in the two mol­ecules. The mol­ecules form π–π dimers of inter­mediary strength with a mean plane separation of 3.36 (2) Å. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435609/ /pubmed/22969482 http://dx.doi.org/10.1107/S1600536812035726 Text en © Mathias O. Senge 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Senge, Mathias O.
[5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II)
title [5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II)
title_full [5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II)
title_fullStr [5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II)
title_full_unstemmed [5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II)
title_short [5,15-Bis(2-methyl­prop­yl)porphyrinato]nickel(II)
title_sort [5,15-bis(2-methyl­prop­yl)porphyrinato]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435609/
https://www.ncbi.nlm.nih.gov/pubmed/22969482
http://dx.doi.org/10.1107/S1600536812035726
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