trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate

In the title compound, [RuCl(2)(C(4)H(4)N(2))(4)]·2CH(2)Cl(2), the Ru(II) atom occupies a position of 222 symmetry and the C atom of the solvent mol­ecule occupies a site with twofold symmetry. The Ru(II) atom has a slightly distorted octa­hedral geometry. The pyrazine rings are propeller-like and r...

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Detalles Bibliográficos
Autores principales: Nesterov, Vladimir N., Khan, Wajiha, Rangel, Alexandra E., Smucker, Bradley W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435610/
https://www.ncbi.nlm.nih.gov/pubmed/22969483
http://dx.doi.org/10.1107/S1600536812035817
Descripción
Sumario:In the title compound, [RuCl(2)(C(4)H(4)N(2))(4)]·2CH(2)Cl(2), the Ru(II) atom occupies a position of 222 symmetry and the C atom of the solvent mol­ecule occupies a site with twofold symmetry. The Ru(II) atom has a slightly distorted octa­hedral geometry. The pyrazine rings are propeller-like and rotated 45.1 (1)° from the RuN(4) plane. In the crystal, the complex and solvent mol­ecules are bridged by weak C—H⋯N hydrogen bonds along the c axis. Weak inter­molecular C—H⋯Cl contacts link the complexes in the ab plane, forming a network.

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