trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate

In the title compound, [RuCl(2)(C(4)H(4)N(2))(4)]·2CH(2)Cl(2), the Ru(II) atom occupies a position of 222 symmetry and the C atom of the solvent mol­ecule occupies a site with twofold symmetry. The Ru(II) atom has a slightly distorted octa­hedral geometry. The pyrazine rings are propeller-like and r...

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Autores principales: Nesterov, Vladimir N., Khan, Wajiha, Rangel, Alexandra E., Smucker, Bradley W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435610/
https://www.ncbi.nlm.nih.gov/pubmed/22969483
http://dx.doi.org/10.1107/S1600536812035817
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author Nesterov, Vladimir N.
Khan, Wajiha
Rangel, Alexandra E.
Smucker, Bradley W.
author_facet Nesterov, Vladimir N.
Khan, Wajiha
Rangel, Alexandra E.
Smucker, Bradley W.
author_sort Nesterov, Vladimir N.
collection PubMed
description In the title compound, [RuCl(2)(C(4)H(4)N(2))(4)]·2CH(2)Cl(2), the Ru(II) atom occupies a position of 222 symmetry and the C atom of the solvent mol­ecule occupies a site with twofold symmetry. The Ru(II) atom has a slightly distorted octa­hedral geometry. The pyrazine rings are propeller-like and rotated 45.1 (1)° from the RuN(4) plane. In the crystal, the complex and solvent mol­ecules are bridged by weak C—H⋯N hydrogen bonds along the c axis. Weak inter­molecular C—H⋯Cl contacts link the complexes in the ab plane, forming a network.
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spelling pubmed-34356102012-09-11 trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate Nesterov, Vladimir N. Khan, Wajiha Rangel, Alexandra E. Smucker, Bradley W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(2)(C(4)H(4)N(2))(4)]·2CH(2)Cl(2), the Ru(II) atom occupies a position of 222 symmetry and the C atom of the solvent mol­ecule occupies a site with twofold symmetry. The Ru(II) atom has a slightly distorted octa­hedral geometry. The pyrazine rings are propeller-like and rotated 45.1 (1)° from the RuN(4) plane. In the crystal, the complex and solvent mol­ecules are bridged by weak C—H⋯N hydrogen bonds along the c axis. Weak inter­molecular C—H⋯Cl contacts link the complexes in the ab plane, forming a network. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435610/ /pubmed/22969483 http://dx.doi.org/10.1107/S1600536812035817 Text en © Nesterov et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nesterov, Vladimir N.
Khan, Wajiha
Rangel, Alexandra E.
Smucker, Bradley W.
trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate
title trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate
title_full trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate
title_fullStr trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate
title_full_unstemmed trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate
title_short trans-Dichloridotetra­pyrazine­ruthenium(II) dichloro­methane disolvate
title_sort trans-dichloridotetra­pyrazine­ruthenium(ii) dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435610/
https://www.ncbi.nlm.nih.gov/pubmed/22969483
http://dx.doi.org/10.1107/S1600536812035817
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AT smuckerbradleyw transdichloridotetrapyrazinerutheniumiidichloromethanedisolvate

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