Cargando…
{2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ(2) N (1),O]-5-methoxyphenolato-κO (1)}chloridocopper(II)
The asymmetric unit of the title compound, [Cu(C(9)H(10)N(3)O(3))Cl], contains two independent molecules with similar structures. The Cu(II) cation is N,O,O′-chelated by the deprotonated Schiff base ligand and is further coordinated by a Cl(−) anion in a distorted ClNO(2) square-planar geometry. In...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435611/ https://www.ncbi.nlm.nih.gov/pubmed/22969484 http://dx.doi.org/10.1107/S160053681203574X |
| _version_ | 1782242551689904128 |
|---|---|
| author | Kunnath, Roji J. Prathapachandra Kurup, M. R. Ng, Seik Weng |
| author_facet | Kunnath, Roji J. Prathapachandra Kurup, M. R. Ng, Seik Weng |
| author_sort | Kunnath, Roji J. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Cu(C(9)H(10)N(3)O(3))Cl], contains two independent molecules with similar structures. The Cu(II) cation is N,O,O′-chelated by the deprotonated Schiff base ligand and is further coordinated by a Cl(−) anion in a distorted ClNO(2) square-planar geometry. In the crystal, adjacent molecules are linked by N—H⋯O and N—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to [100]. |
| format | Online Article Text |
| id | pubmed-3435611 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34356112012-09-11 {2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ(2) N (1),O]-5-methoxyphenolato-κO (1)}chloridocopper(II) Kunnath, Roji J. Prathapachandra Kurup, M. R. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(9)H(10)N(3)O(3))Cl], contains two independent molecules with similar structures. The Cu(II) cation is N,O,O′-chelated by the deprotonated Schiff base ligand and is further coordinated by a Cl(−) anion in a distorted ClNO(2) square-planar geometry. In the crystal, adjacent molecules are linked by N—H⋯O and N—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to [100]. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435611/ /pubmed/22969484 http://dx.doi.org/10.1107/S160053681203574X Text en © Kunnath et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kunnath, Roji J. Prathapachandra Kurup, M. R. Ng, Seik Weng {2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ(2) N (1),O]-5-methoxyphenolato-κO (1)}chloridocopper(II) |
| title | {2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ(2)
N
(1),O]-5-methoxyphenolato-κO
(1)}chloridocopper(II) |
| title_full | {2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ(2)
N
(1),O]-5-methoxyphenolato-κO
(1)}chloridocopper(II) |
| title_fullStr | {2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ(2)
N
(1),O]-5-methoxyphenolato-κO
(1)}chloridocopper(II) |
| title_full_unstemmed | {2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ(2)
N
(1),O]-5-methoxyphenolato-κO
(1)}chloridocopper(II) |
| title_short | {2-[(2-Carbamoylhydrazin-1-ylidene)methyl-κ(2)
N
(1),O]-5-methoxyphenolato-κO
(1)}chloridocopper(II) |
| title_sort | {2-[(2-carbamoylhydrazin-1-ylidene)methyl-κ(2)
n
(1),o]-5-methoxyphenolato-κo
(1)}chloridocopper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435611/ https://www.ncbi.nlm.nih.gov/pubmed/22969484 http://dx.doi.org/10.1107/S160053681203574X |
| work_keys_str_mv | AT kunnathrojij 22carbamoylhydrazin1ylidenemethylk2n1o5methoxyphenolatoko1chloridocopperii AT prathapachandrakurupmr 22carbamoylhydrazin1ylidenemethylk2n1o5methoxyphenolatoko1chloridocopperii AT ngseikweng 22carbamoylhydrazin1ylidenemethylk2n1o5methoxyphenolatoko1chloridocopperii |