Poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(II)]

In the title polymeric compound, [Pb(C(12)H(6)N(2)O(4))](n), the Pb(II) cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′-dicarboxyl­ate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N(2)O(6) geometry. The...

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Autores principales: Sertçelik, Mustafa, Çaylak Delibaş, Nagihan, Çevik, Sabri, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435613/
https://www.ncbi.nlm.nih.gov/pubmed/22969486
http://dx.doi.org/10.1107/S1600536812035647
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author Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Çevik, Sabri
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Çevik, Sabri
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Sertçelik, Mustafa
collection PubMed
description In the title polymeric compound, [Pb(C(12)H(6)N(2)O(4))](n), the Pb(II) cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′-dicarboxyl­ate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N(2)O(6) geometry. The carboxylate groups bridge the Pb(II) cations, forming a three-dimensional polymeric structure. The carboxyl­ate group is twisted away from the attached pyridine ring by 11.4 (3)°.
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spelling pubmed-34356132012-09-11 Poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(II)] Sertçelik, Mustafa Çaylak Delibaş, Nagihan Çevik, Sabri Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Pb(C(12)H(6)N(2)O(4))](n), the Pb(II) cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′-dicarboxyl­ate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N(2)O(6) geometry. The carboxylate groups bridge the Pb(II) cations, forming a three-dimensional polymeric structure. The carboxyl­ate group is twisted away from the attached pyridine ring by 11.4 (3)°. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435613/ /pubmed/22969486 http://dx.doi.org/10.1107/S1600536812035647 Text en © Sertçelik et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Çevik, Sabri
Necefoğlu, Hacali
Hökelek, Tuncer
Poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(II)]
title Poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(II)]
title_full Poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(II)]
title_fullStr Poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(II)]
title_full_unstemmed Poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(II)]
title_short Poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(II)]
title_sort poly[(μ(5)-2,2′-bipyridine-5,5′-dicarboxyl­ato)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435613/
https://www.ncbi.nlm.nih.gov/pubmed/22969486
http://dx.doi.org/10.1107/S1600536812035647
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