Dimorpholinium tetra­chlorido­cobaltate(II)

In the title mol­ecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetra­chloridocobaltate(II) anion is significantly distorted from regular tetra­hedral geometry [Cl—Co—Cl = 102.183 (19)–117.59 (2)°]. The Co—Cl bond lengths for the chloride ions not...

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Detalles Bibliográficos
Autores principales: Cao, Xing-Xing, Cheng, He-Long, Feng, Qing-Liu, Chen, Li-Zhuang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435614/
https://www.ncbi.nlm.nih.gov/pubmed/22969487
http://dx.doi.org/10.1107/S1600536812035830
Descripción
Sumario:In the title mol­ecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetra­chloridocobaltate(II) anion is significantly distorted from regular tetra­hedral geometry [Cl—Co—Cl = 102.183 (19)–117.59 (2)°]. The Co—Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N—H⋯O and N—H⋯Cl and bifurcated N—H⋯(O,Cl) hydrogen bonds to generate (100) sheets.

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