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Dimorpholinium tetrachloridocobaltate(II)
In the title molecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetrachloridocobaltate(II) anion is significantly distorted from regular tetrahedral geometry [Cl—Co—Cl = 102.183 (19)–117.59 (2)°]. The Co—Cl bond lengths for the chloride ions not...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435614/ https://www.ncbi.nlm.nih.gov/pubmed/22969487 http://dx.doi.org/10.1107/S1600536812035830 |
| _version_ | 1782242552410275840 |
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| author | Cao, Xing-Xing Cheng, He-Long Feng, Qing-Liu Chen, Li-Zhuang |
| author_facet | Cao, Xing-Xing Cheng, He-Long Feng, Qing-Liu Chen, Li-Zhuang |
| author_sort | Cao, Xing-Xing |
| collection | PubMed |
| description | In the title molecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetrachloridocobaltate(II) anion is significantly distorted from regular tetrahedral geometry [Cl—Co—Cl = 102.183 (19)–117.59 (2)°]. The Co—Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N—H⋯O and N—H⋯Cl and bifurcated N—H⋯(O,Cl) hydrogen bonds to generate (100) sheets. |
| format | Online Article Text |
| id | pubmed-3435614 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34356142012-09-11 Dimorpholinium tetrachloridocobaltate(II) Cao, Xing-Xing Cheng, He-Long Feng, Qing-Liu Chen, Li-Zhuang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title molecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetrachloridocobaltate(II) anion is significantly distorted from regular tetrahedral geometry [Cl—Co—Cl = 102.183 (19)–117.59 (2)°]. The Co—Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N—H⋯O and N—H⋯Cl and bifurcated N—H⋯(O,Cl) hydrogen bonds to generate (100) sheets. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435614/ /pubmed/22969487 http://dx.doi.org/10.1107/S1600536812035830 Text en © Cao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cao, Xing-Xing Cheng, He-Long Feng, Qing-Liu Chen, Li-Zhuang Dimorpholinium tetrachloridocobaltate(II) |
| title | Dimorpholinium tetrachloridocobaltate(II) |
| title_full | Dimorpholinium tetrachloridocobaltate(II) |
| title_fullStr | Dimorpholinium tetrachloridocobaltate(II) |
| title_full_unstemmed | Dimorpholinium tetrachloridocobaltate(II) |
| title_short | Dimorpholinium tetrachloridocobaltate(II) |
| title_sort | dimorpholinium tetrachloridocobaltate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435614/ https://www.ncbi.nlm.nih.gov/pubmed/22969487 http://dx.doi.org/10.1107/S1600536812035830 |
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