fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) O,P]rhenium(I)

The structure of the title complex, [ReBr(C(13)H(19)OP)(CO)(3)], displays a facial coordination of the three CO ligands and a κ(2) O,P coordination mode of the 2-diisopropyl­phosphino­benzaldehyde ligands. The Re—C bond distance for the CO ligand trans to the P atom is, due to its trans influence, e...

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Detalles Bibliográficos
Autores principales: Apostolidis, Christos, Ahlmann, Martin, Walter, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435616/
https://www.ncbi.nlm.nih.gov/pubmed/22969489
http://dx.doi.org/10.1107/S1600536812035957
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author Apostolidis, Christos
Ahlmann, Martin
Walter, Olaf
author_facet Apostolidis, Christos
Ahlmann, Martin
Walter, Olaf
author_sort Apostolidis, Christos
collection PubMed
description The structure of the title complex, [ReBr(C(13)H(19)OP)(CO)(3)], displays a facial coordination of the three CO ligands and a κ(2) O,P coordination mode of the 2-diisopropyl­phosphino­benzaldehyde ligands. The Re—C bond distance for the CO ligand trans to the P atom is, due to its trans influence, elongated to 1.943 (3) Å, showing that this CO ligand is more weakly bound to the Re centre than the other two.
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spelling pubmed-34356162012-09-11 fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) O,P]rhenium(I) Apostolidis, Christos Ahlmann, Martin Walter, Olaf Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title complex, [ReBr(C(13)H(19)OP)(CO)(3)], displays a facial coordination of the three CO ligands and a κ(2) O,P coordination mode of the 2-diisopropyl­phosphino­benzaldehyde ligands. The Re—C bond distance for the CO ligand trans to the P atom is, due to its trans influence, elongated to 1.943 (3) Å, showing that this CO ligand is more weakly bound to the Re centre than the other two. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435616/ /pubmed/22969489 http://dx.doi.org/10.1107/S1600536812035957 Text en © Apostolidis et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Apostolidis, Christos
Ahlmann, Martin
Walter, Olaf
fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) O,P]rhenium(I)
title fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) O,P]rhenium(I)
title_full fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) O,P]rhenium(I)
title_fullStr fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) O,P]rhenium(I)
title_full_unstemmed fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) O,P]rhenium(I)
title_short fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) O,P]rhenium(I)
title_sort fac-bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2) o,p]rhenium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435616/
https://www.ncbi.nlm.nih.gov/pubmed/22969489
http://dx.doi.org/10.1107/S1600536812035957
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AT walterolaf facbromidotricarbonyl2diisopropylphosphanylbenzaldehydek2oprheniumi

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