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Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate
In the title compound, [Mn(C(13)H(16)N(6)O)(CO)(3)](CF(3)O(3)S), the Mn(I) atom has a slightly distorted octahedral geometry. The three CO ligands have C—Mn—C angles in the range 89.44 (10)–92.31 (9)°, while the three N atoms of the tripodal ligand form significantly smaller N—Mn—N angles of 82.76 ...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435617/ https://www.ncbi.nlm.nih.gov/pubmed/22969490 http://dx.doi.org/10.1107/S1600536812035891 |
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author | Reiss, Guido J. Kunz, Peter C. |
author_facet | Reiss, Guido J. Kunz, Peter C. |
author_sort | Reiss, Guido J. |
collection | PubMed |
description | In the title compound, [Mn(C(13)H(16)N(6)O)(CO)(3)](CF(3)O(3)S), the Mn(I) atom has a slightly distorted octahedral geometry. The three CO ligands have C—Mn—C angles in the range 89.44 (10)–92.31 (9)°, while the three N atoms of the tripodal ligand form significantly smaller N—Mn—N angles of 82.76 (2)–85.51 (6)°. The three N atoms of the tripodal ligand and the three carbonyl ligands coordinate facially. In the crystal, the trifluoromethanesulfonate counter anion is connected by a medium-strength O—H⋯O hydrogen bond to the hydroxyl group of the manganese complex. |
format | Online Article Text |
id | pubmed-3435617 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34356172012-09-11 Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate Reiss, Guido J. Kunz, Peter C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(13)H(16)N(6)O)(CO)(3)](CF(3)O(3)S), the Mn(I) atom has a slightly distorted octahedral geometry. The three CO ligands have C—Mn—C angles in the range 89.44 (10)–92.31 (9)°, while the three N atoms of the tripodal ligand form significantly smaller N—Mn—N angles of 82.76 (2)–85.51 (6)°. The three N atoms of the tripodal ligand and the three carbonyl ligands coordinate facially. In the crystal, the trifluoromethanesulfonate counter anion is connected by a medium-strength O—H⋯O hydrogen bond to the hydroxyl group of the manganese complex. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435617/ /pubmed/22969490 http://dx.doi.org/10.1107/S1600536812035891 Text en © Reiss and Kunz 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Reiss, Guido J. Kunz, Peter C. Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate |
title | Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN
(3))methanol]manganese(I) trifluoromethanesulfonate |
title_full | Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN
(3))methanol]manganese(I) trifluoromethanesulfonate |
title_fullStr | Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN
(3))methanol]manganese(I) trifluoromethanesulfonate |
title_full_unstemmed | Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN
(3))methanol]manganese(I) trifluoromethanesulfonate |
title_short | Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN
(3))methanol]manganese(I) trifluoromethanesulfonate |
title_sort | tricarbonyl[tris(1-methyl-1h-imidazol-2-yl-κn
(3))methanol]manganese(i) trifluoromethanesulfonate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435617/ https://www.ncbi.nlm.nih.gov/pubmed/22969490 http://dx.doi.org/10.1107/S1600536812035891 |
work_keys_str_mv | AT reissguidoj tricarbonyltris1methyl1himidazol2ylkn3methanolmanganeseitrifluoromethanesulfonate AT kunzpeterc tricarbonyltris1methyl1himidazol2ylkn3methanolmanganeseitrifluoromethanesulfonate |