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Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate

In the title compound, [Mn(C(13)H(16)N(6)O)(CO)(3)](CF(3)O(3)S), the Mn(I) atom has a slightly distorted octa­hedral geometry. The three CO ligands have C—Mn—C angles in the range 89.44 (10)–92.31 (9)°, while the three N atoms of the tripodal ligand form significantly smaller N—Mn—N angles of 82.76 ...

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Detalles Bibliográficos
Autores principales: Reiss, Guido J., Kunz, Peter C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435617/
https://www.ncbi.nlm.nih.gov/pubmed/22969490
http://dx.doi.org/10.1107/S1600536812035891
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author Reiss, Guido J.
Kunz, Peter C.
author_facet Reiss, Guido J.
Kunz, Peter C.
author_sort Reiss, Guido J.
collection PubMed
description In the title compound, [Mn(C(13)H(16)N(6)O)(CO)(3)](CF(3)O(3)S), the Mn(I) atom has a slightly distorted octa­hedral geometry. The three CO ligands have C—Mn—C angles in the range 89.44 (10)–92.31 (9)°, while the three N atoms of the tripodal ligand form significantly smaller N—Mn—N angles of 82.76 (2)–85.51 (6)°. The three N atoms of the tripodal ligand and the three carbonyl ligands coordinate facially. In the crystal, the trifluoro­methane­sulfonate counter anion is connected by a medium-strength O—H⋯O hydrogen bond to the hydroxyl group of the manganese complex.
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spelling pubmed-34356172012-09-11 Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate Reiss, Guido J. Kunz, Peter C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(13)H(16)N(6)O)(CO)(3)](CF(3)O(3)S), the Mn(I) atom has a slightly distorted octa­hedral geometry. The three CO ligands have C—Mn—C angles in the range 89.44 (10)–92.31 (9)°, while the three N atoms of the tripodal ligand form significantly smaller N—Mn—N angles of 82.76 (2)–85.51 (6)°. The three N atoms of the tripodal ligand and the three carbonyl ligands coordinate facially. In the crystal, the trifluoro­methane­sulfonate counter anion is connected by a medium-strength O—H⋯O hydrogen bond to the hydroxyl group of the manganese complex. International Union of Crystallography 2012-08-23 /pmc/articles/PMC3435617/ /pubmed/22969490 http://dx.doi.org/10.1107/S1600536812035891 Text en © Reiss and Kunz 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reiss, Guido J.
Kunz, Peter C.
Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate
title Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate
title_full Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate
title_fullStr Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate
title_full_unstemmed Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate
title_short Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN (3))methanol]manganese(I) trifluoromethanesulfonate
title_sort tricarbonyl[tris(1-methyl-1h-imidazol-2-yl-κn (3))methanol]manganese(i) trifluoromethanesulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435617/
https://www.ncbi.nlm.nih.gov/pubmed/22969490
http://dx.doi.org/10.1107/S1600536812035891
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