Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate

In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa­hedral coordination geometry defined by a tridentate cyclo­metalated NCN ligand and three Cl atoms. In the crystal, individual mol­ecules are aggregated into a three-dimensional network by C—H⋯Cl hydroge...

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Detalles Bibliográficos
Autores principales: Wu, Yang, Xie, Dahai, Zhang, Dengqing, Li, Xianying, Jin, Wusong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435621/
https://www.ncbi.nlm.nih.gov/pubmed/22969494
http://dx.doi.org/10.1107/S1600536812036410
Descripción
Sumario:In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa­hedral coordination geometry defined by a tridentate cyclo­metalated NCN ligand and three Cl atoms. In the crystal, individual mol­ecules are aggregated into a three-dimensional network by C—H⋯Cl hydrogen-bonding inter­actions and π–π stacking inter­actions between the tridentate ligands, the shortest ring centroid–centroid distance being 3.613 Å.

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