Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate

In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa­hedral coordination geometry defined by a tridentate cyclo­metalated NCN ligand and three Cl atoms. In the crystal, individual mol­ecules are aggregated into a three-dimensional network by C—H⋯Cl hydroge...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Yang, Xie, Dahai, Zhang, Dengqing, Li, Xianying, Jin, Wusong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435621/
https://www.ncbi.nlm.nih.gov/pubmed/22969494
http://dx.doi.org/10.1107/S1600536812036410
_version_ 1782242554046054400
author Wu, Yang
Xie, Dahai
Zhang, Dengqing
Li, Xianying
Jin, Wusong
author_facet Wu, Yang
Xie, Dahai
Zhang, Dengqing
Li, Xianying
Jin, Wusong
author_sort Wu, Yang
collection PubMed
description In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa­hedral coordination geometry defined by a tridentate cyclo­metalated NCN ligand and three Cl atoms. In the crystal, individual mol­ecules are aggregated into a three-dimensional network by C—H⋯Cl hydrogen-bonding inter­actions and π–π stacking inter­actions between the tridentate ligands, the shortest ring centroid–centroid distance being 3.613 Å.
format Online
Article
Text
id pubmed-3435621
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34356212012-09-11 Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate Wu, Yang Xie, Dahai Zhang, Dengqing Li, Xianying Jin, Wusong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa­hedral coordination geometry defined by a tridentate cyclo­metalated NCN ligand and three Cl atoms. In the crystal, individual mol­ecules are aggregated into a three-dimensional network by C—H⋯Cl hydrogen-bonding inter­actions and π–π stacking inter­actions between the tridentate ligands, the shortest ring centroid–centroid distance being 3.613 Å. International Union of Crystallography 2012-08-25 /pmc/articles/PMC3435621/ /pubmed/22969494 http://dx.doi.org/10.1107/S1600536812036410 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Yang
Xie, Dahai
Zhang, Dengqing
Li, Xianying
Jin, Wusong
Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate
title Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate
title_full Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate
title_fullStr Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate
title_full_unstemmed Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate
title_short Trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κN)phenyl-κC (1)]platinum(IV) acetonitrile monosolvate
title_sort trichlorido[4-meth­oxy-2,6-bis­(2-pyrimidin-2-yl-κn)phenyl-κc (1)]platinum(iv) acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435621/
https://www.ncbi.nlm.nih.gov/pubmed/22969494
http://dx.doi.org/10.1107/S1600536812036410
work_keys_str_mv AT wuyang trichlorido4methoxy26bis2pyrimidin2ylknphenylkc1platinumivacetonitrilemonosolvate
AT xiedahai trichlorido4methoxy26bis2pyrimidin2ylknphenylkc1platinumivacetonitrilemonosolvate
AT zhangdengqing trichlorido4methoxy26bis2pyrimidin2ylknphenylkc1platinumivacetonitrilemonosolvate
AT lixianying trichlorido4methoxy26bis2pyrimidin2ylknphenylkc1platinumivacetonitrilemonosolvate
AT jinwusong trichlorido4methoxy26bis2pyrimidin2ylknphenylkc1platinumivacetonitrilemonosolvate

Ejemplares similares