(2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2)

The asymmetric unit of the title compound, [Co(C(36)H(44)N(4))]·2C(7)H(5)NO(3), is composed of one half of the complex, arranged about an inversion center, and a complete 2-nitro­benzaldehyde (NBA) mol­ecule. The structure consists of columns that contain inter­leaved mol­ecules of NBA and [Co(II)(O...

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Detalles Bibliográficos
Autores principales: Mansour, Anissa, Daran, Jean-Claude, Nasri, Habib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435623/
https://www.ncbi.nlm.nih.gov/pubmed/22969496
http://dx.doi.org/10.1107/S1600536812036112
Descripción
Sumario:The asymmetric unit of the title compound, [Co(C(36)H(44)N(4))]·2C(7)H(5)NO(3), is composed of one half of the complex, arranged about an inversion center, and a complete 2-nitro­benzaldehyde (NBA) mol­ecule. The structure consists of columns that contain inter­leaved mol­ecules of NBA and [Co(II)(OEP)] (OEP is 2,3,7,8,12,13,17,18-octa­ethyl­porphyrin), which are stacked along the a axis. The Co(II) atom is involved in a π inter­action with the ring of the NBA mol­ecule with a centroid–metal distance of 3.508 (6) Å. There is an intra­molecular C—H⋯O hydrogen bond in the NBA mol­ecule.

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