(2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2)

The asymmetric unit of the title compound, [Co(C(36)H(44)N(4))]·2C(7)H(5)NO(3), is composed of one half of the complex, arranged about an inversion center, and a complete 2-nitro­benzaldehyde (NBA) mol­ecule. The structure consists of columns that contain inter­leaved mol­ecules of NBA and [Co(II)(O...

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Detalles Bibliográficos
Autores principales: Mansour, Anissa, Daran, Jean-Claude, Nasri, Habib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435623/
https://www.ncbi.nlm.nih.gov/pubmed/22969496
http://dx.doi.org/10.1107/S1600536812036112
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author Mansour, Anissa
Daran, Jean-Claude
Nasri, Habib
author_facet Mansour, Anissa
Daran, Jean-Claude
Nasri, Habib
author_sort Mansour, Anissa
collection PubMed
description The asymmetric unit of the title compound, [Co(C(36)H(44)N(4))]·2C(7)H(5)NO(3), is composed of one half of the complex, arranged about an inversion center, and a complete 2-nitro­benzaldehyde (NBA) mol­ecule. The structure consists of columns that contain inter­leaved mol­ecules of NBA and [Co(II)(OEP)] (OEP is 2,3,7,8,12,13,17,18-octa­ethyl­porphyrin), which are stacked along the a axis. The Co(II) atom is involved in a π inter­action with the ring of the NBA mol­ecule with a centroid–metal distance of 3.508 (6) Å. There is an intra­molecular C—H⋯O hydrogen bond in the NBA mol­ecule.
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spelling pubmed-34356232012-09-11 (2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2) Mansour, Anissa Daran, Jean-Claude Nasri, Habib Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(C(36)H(44)N(4))]·2C(7)H(5)NO(3), is composed of one half of the complex, arranged about an inversion center, and a complete 2-nitro­benzaldehyde (NBA) mol­ecule. The structure consists of columns that contain inter­leaved mol­ecules of NBA and [Co(II)(OEP)] (OEP is 2,3,7,8,12,13,17,18-octa­ethyl­porphyrin), which are stacked along the a axis. The Co(II) atom is involved in a π inter­action with the ring of the NBA mol­ecule with a centroid–metal distance of 3.508 (6) Å. There is an intra­molecular C—H⋯O hydrogen bond in the NBA mol­ecule. International Union of Crystallography 2012-08-25 /pmc/articles/PMC3435623/ /pubmed/22969496 http://dx.doi.org/10.1107/S1600536812036112 Text en © Mansour et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mansour, Anissa
Daran, Jean-Claude
Nasri, Habib
(2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2)
title (2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2)
title_full (2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2)
title_fullStr (2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2)
title_full_unstemmed (2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2)
title_short (2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ(4) N)cobalt(II)–2-nitro­benzaldehyde (1/2)
title_sort (2,3,7,8,12,13,17,18-octa­ethyl­porphyrinato-κ(4) n)cobalt(ii)–2-nitro­benzaldehyde (1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435623/
https://www.ncbi.nlm.nih.gov/pubmed/22969496
http://dx.doi.org/10.1107/S1600536812036112
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AT nasrihabib 237812131718octaethylporphyrinatok4ncobaltii2nitrobenzaldehyde12

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