Bis[μ-N′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(N,N-dimethyl­formamide)­copper(II)]

The title compound, [Cu(2)(C(15)H(11)BrN(2)O(4))(2)(C(3)H(7)NO)(2)], is derived from the reaction of N′-(5-bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-2-hy­droxy­benzohydrazide and copper nitrate in a dimethyl­formamide solution in the presence of sodium hydroxide. The compound can be regarded as a bi...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Shunsheng, Li, Lanlan, Liu, Xiangrong, Feng, Weixu, Lü, Xingqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435625/
https://www.ncbi.nlm.nih.gov/pubmed/22969498
http://dx.doi.org/10.1107/S1600536812036100
_version_ 1782242554982432768
author Zhao, Shunsheng
Li, Lanlan
Liu, Xiangrong
Feng, Weixu
Lü, Xingqiang
author_facet Zhao, Shunsheng
Li, Lanlan
Liu, Xiangrong
Feng, Weixu
Lü, Xingqiang
author_sort Zhao, Shunsheng
collection PubMed
description The title compound, [Cu(2)(C(15)H(11)BrN(2)O(4))(2)(C(3)H(7)NO)(2)], is derived from the reaction of N′-(5-bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-2-hy­droxy­benzohydrazide and copper nitrate in a dimethyl­formamide solution in the presence of sodium hydroxide. The compound can be regarded as a binuclear centrosymmetric complex. In the crystal, the Cu(II) atom is fivefold surrounded and adopts a distorted square-pyramidal coordination environment. An intra­molecular O—H⋯N hydrogen bond stabilizes the mol­ecular conformation.
format Online
Article
Text
id pubmed-3435625
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34356252012-09-11 Bis[μ-N′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(N,N-dimethyl­formamide)­copper(II)] Zhao, Shunsheng Li, Lanlan Liu, Xiangrong Feng, Weixu Lü, Xingqiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(15)H(11)BrN(2)O(4))(2)(C(3)H(7)NO)(2)], is derived from the reaction of N′-(5-bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-2-hy­droxy­benzohydrazide and copper nitrate in a dimethyl­formamide solution in the presence of sodium hydroxide. The compound can be regarded as a binuclear centrosymmetric complex. In the crystal, the Cu(II) atom is fivefold surrounded and adopts a distorted square-pyramidal coordination environment. An intra­molecular O—H⋯N hydrogen bond stabilizes the mol­ecular conformation. International Union of Crystallography 2012-08-25 /pmc/articles/PMC3435625/ /pubmed/22969498 http://dx.doi.org/10.1107/S1600536812036100 Text en © Zhao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Shunsheng
Li, Lanlan
Liu, Xiangrong
Feng, Weixu
Lü, Xingqiang
Bis[μ-N′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(N,N-dimethyl­formamide)­copper(II)]
title Bis[μ-N′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(N,N-dimethyl­formamide)­copper(II)]
title_full Bis[μ-N′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(N,N-dimethyl­formamide)­copper(II)]
title_fullStr Bis[μ-N′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(N,N-dimethyl­formamide)­copper(II)]
title_full_unstemmed Bis[μ-N′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(N,N-dimethyl­formamide)­copper(II)]
title_short Bis[μ-N′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(N,N-dimethyl­formamide)­copper(II)]
title_sort bis[μ-n′-(5-bromo-3-meth­oxy-2-oxido­benzyl­idene)-2-hydroxybenzohydra­zidato]bis[(n,n-dimethyl­formamide)­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435625/
https://www.ncbi.nlm.nih.gov/pubmed/22969498
http://dx.doi.org/10.1107/S1600536812036100
work_keys_str_mv AT zhaoshunsheng bismn5bromo3methoxy2oxidobenzylidene2hydroxybenzohydrazidatobisnndimethylformamidecopperii
AT lilanlan bismn5bromo3methoxy2oxidobenzylidene2hydroxybenzohydrazidatobisnndimethylformamidecopperii
AT liuxiangrong bismn5bromo3methoxy2oxidobenzylidene2hydroxybenzohydrazidatobisnndimethylformamidecopperii
AT fengweixu bismn5bromo3methoxy2oxidobenzylidene2hydroxybenzohydrazidatobisnndimethylformamidecopperii
AT luxingqiang bismn5bromo3methoxy2oxidobenzylidene2hydroxybenzohydrazidatobisnndimethylformamidecopperii

Ejemplares similares