Bis[(cyanido-κC)bis(1,10-phenanthroline-κ(2) N,N′)copper(II)] pentakis­(cyanido-κC)nitro­soferrate(II) dimethyl­formamide monosolvate

The title compound, [Cu(CN)(C(12)H(8)N(2))(2)](2)[Fe(CN)(5)(NO)]·C(3)H(7)NO, is formed of discrete [Cu(phen)(2)CN](+) cations (phen is 1,10-phenanthroline), nitro­prusside [Fe(CN)(5)(NO)](2−) anions and dimethyl­formamide (DMF) mol­ecules of crystallization. The metal atom has a distorted trigonal–b...

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Detalles Bibliográficos
Autores principales: Kozachuk, Olesia V., Kokozay, Vladimir N., Vassilyeva, Olga Yu., Skelton, Brian W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435627/
https://www.ncbi.nlm.nih.gov/pubmed/22969500
http://dx.doi.org/10.1107/S1600536812036264
Descripción
Sumario:The title compound, [Cu(CN)(C(12)H(8)N(2))(2)](2)[Fe(CN)(5)(NO)]·C(3)H(7)NO, is formed of discrete [Cu(phen)(2)CN](+) cations (phen is 1,10-phenanthroline), nitro­prusside [Fe(CN)(5)(NO)](2−) anions and dimethyl­formamide (DMF) mol­ecules of crystallization. The metal atom has a distorted trigonal–bipyra­midal coordination environment, defined by four N atoms of two phen mol­ecules and a C atom of the cyanide group (in the equatorial position). The [Fe(CN)(5)(NO)](2−) anion was found to be disordered about (but not on) a crystallographic twofold rotation axis. Geometries were restrained to ideal values. The dimethyl­formamide solvent mol­ecule was found to be disordered about a crystallographic inversion centre.

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