rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate

In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octa­hedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating...

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Detalles Bibliográficos
Autores principales: Domski, Gregory J., Pecak, Wiktoria H., Swenson, Dale C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435630/
https://www.ncbi.nlm.nih.gov/pubmed/22969503
http://dx.doi.org/10.1107/S1600536812036665
Descripción
Sumario:In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octa­hedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating in a meridional fashion. This complex is of inter­est with respect to transfer hydrogenation catalysis and also provides an example of C—H activation behavior in late transition metal complexes. The dichloro­methane solvent mol­ecule is disordered over two sets of sites with an occupancy ratio of 0.873 (14):0.127 (14).

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