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rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate

In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octa­hedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating...

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Detalles Bibliográficos
Autores principales: Domski, Gregory J., Pecak, Wiktoria H., Swenson, Dale C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435630/
https://www.ncbi.nlm.nih.gov/pubmed/22969503
http://dx.doi.org/10.1107/S1600536812036665
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author Domski, Gregory J.
Pecak, Wiktoria H.
Swenson, Dale C.
author_facet Domski, Gregory J.
Pecak, Wiktoria H.
Swenson, Dale C.
author_sort Domski, Gregory J.
collection PubMed
description In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octa­hedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating in a meridional fashion. This complex is of inter­est with respect to transfer hydrogenation catalysis and also provides an example of C—H activation behavior in late transition metal complexes. The dichloro­methane solvent mol­ecule is disordered over two sets of sites with an occupancy ratio of 0.873 (14):0.127 (14).
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spelling pubmed-34356302012-09-11 rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate Domski, Gregory J. Pecak, Wiktoria H. Swenson, Dale C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octa­hedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating in a meridional fashion. This complex is of inter­est with respect to transfer hydrogenation catalysis and also provides an example of C—H activation behavior in late transition metal complexes. The dichloro­methane solvent mol­ecule is disordered over two sets of sites with an occupancy ratio of 0.873 (14):0.127 (14). International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435630/ /pubmed/22969503 http://dx.doi.org/10.1107/S1600536812036665 Text en © Domski et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Domski, Gregory J.
Pecak, Wiktoria H.
Swenson, Dale C.
rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate
title rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate
title_full rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate
title_fullStr rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate
title_full_unstemmed rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate
title_short rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC (1))imidazol-2-yl­idene-κC (2)}ruthenium(II) dichloro­methane monosolvate
title_sort rac-cis-dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κp)benz­yl]-3-(phenyl-κc (1))imidazol-2-yl­idene-κc (2)}ruthenium(ii) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435630/
https://www.ncbi.nlm.nih.gov/pubmed/22969503
http://dx.doi.org/10.1107/S1600536812036665
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