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rac-cis-Dicarbonylchlorido{1-[2-(diphenylphosphanyl-κP)benzyl]-3-(phenyl-κC (1))imidazol-2-ylidene-κC (2)}ruthenium(II) dichloromethane monosolvate
In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octahedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435630/ https://www.ncbi.nlm.nih.gov/pubmed/22969503 http://dx.doi.org/10.1107/S1600536812036665 |
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author | Domski, Gregory J. Pecak, Wiktoria H. Swenson, Dale C. |
author_facet | Domski, Gregory J. Pecak, Wiktoria H. Swenson, Dale C. |
author_sort | Domski, Gregory J. |
collection | PubMed |
description | In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octahedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating in a meridional fashion. This complex is of interest with respect to transfer hydrogenation catalysis and also provides an example of C—H activation behavior in late transition metal complexes. The dichloromethane solvent molecule is disordered over two sets of sites with an occupancy ratio of 0.873 (14):0.127 (14). |
format | Online Article Text |
id | pubmed-3435630 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34356302012-09-11 rac-cis-Dicarbonylchlorido{1-[2-(diphenylphosphanyl-κP)benzyl]-3-(phenyl-κC (1))imidazol-2-ylidene-κC (2)}ruthenium(II) dichloromethane monosolvate Domski, Gregory J. Pecak, Wiktoria H. Swenson, Dale C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octahedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating in a meridional fashion. This complex is of interest with respect to transfer hydrogenation catalysis and also provides an example of C—H activation behavior in late transition metal complexes. The dichloromethane solvent molecule is disordered over two sets of sites with an occupancy ratio of 0.873 (14):0.127 (14). International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435630/ /pubmed/22969503 http://dx.doi.org/10.1107/S1600536812036665 Text en © Domski et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Domski, Gregory J. Pecak, Wiktoria H. Swenson, Dale C. rac-cis-Dicarbonylchlorido{1-[2-(diphenylphosphanyl-κP)benzyl]-3-(phenyl-κC (1))imidazol-2-ylidene-κC (2)}ruthenium(II) dichloromethane monosolvate |
title |
rac-cis-Dicarbonylchlorido{1-[2-(diphenylphosphanyl-κP)benzyl]-3-(phenyl-κC
(1))imidazol-2-ylidene-κC
(2)}ruthenium(II) dichloromethane monosolvate |
title_full |
rac-cis-Dicarbonylchlorido{1-[2-(diphenylphosphanyl-κP)benzyl]-3-(phenyl-κC
(1))imidazol-2-ylidene-κC
(2)}ruthenium(II) dichloromethane monosolvate |
title_fullStr |
rac-cis-Dicarbonylchlorido{1-[2-(diphenylphosphanyl-κP)benzyl]-3-(phenyl-κC
(1))imidazol-2-ylidene-κC
(2)}ruthenium(II) dichloromethane monosolvate |
title_full_unstemmed |
rac-cis-Dicarbonylchlorido{1-[2-(diphenylphosphanyl-κP)benzyl]-3-(phenyl-κC
(1))imidazol-2-ylidene-κC
(2)}ruthenium(II) dichloromethane monosolvate |
title_short |
rac-cis-Dicarbonylchlorido{1-[2-(diphenylphosphanyl-κP)benzyl]-3-(phenyl-κC
(1))imidazol-2-ylidene-κC
(2)}ruthenium(II) dichloromethane monosolvate |
title_sort | rac-cis-dicarbonylchlorido{1-[2-(diphenylphosphanyl-κp)benzyl]-3-(phenyl-κc
(1))imidazol-2-ylidene-κc
(2)}ruthenium(ii) dichloromethane monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435630/ https://www.ncbi.nlm.nih.gov/pubmed/22969503 http://dx.doi.org/10.1107/S1600536812036665 |
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