Hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) N,N-dimethyl­propionamide penta­solvate

In the asymmetric unit of the title salt, (C(5)H(12)NO)(6)[PMo(12)O(40)](2)·5C(5)H(11)NO, there are two independent α-Keggin-type [PMo(12)O(40)](3−) polyoxidoanions, which show characteristic features with respect to bond lengths and angles. One of the [CH(3)CH(2)C(=OH)N(CH(3))(2)](+) cations is hyd...

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Autores principales: Raissi Shabari, Akbar, Pourayoubi, Mehrdad, Derakhshan Rad, Shadi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435631/
https://www.ncbi.nlm.nih.gov/pubmed/22969504
http://dx.doi.org/10.1107/S1600536812036677
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author Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Derakhshan Rad, Shadi
author_facet Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Derakhshan Rad, Shadi
author_sort Raissi Shabari, Akbar
collection PubMed
description In the asymmetric unit of the title salt, (C(5)H(12)NO)(6)[PMo(12)O(40)](2)·5C(5)H(11)NO, there are two independent α-Keggin-type [PMo(12)O(40)](3−) polyoxidoanions, which show characteristic features with respect to bond lengths and angles. One of the [CH(3)CH(2)C(=OH)N(CH(3))(2)](+) cations is hydrogen bonded to the neighboring polyoxidoanion through a C=O—H⋯O(bridge) hydrogen bond. The organic mol­ecules and the remaining organic cations form [(C(5)H(11)NO)(2)H](+) mol­ecule–cation pairs, two of which lie about inversion centers, through O—H⋯O hydrogen bonds.
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spelling pubmed-34356312012-09-11 Hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) N,N-dimethyl­propionamide penta­solvate Raissi Shabari, Akbar Pourayoubi, Mehrdad Derakhshan Rad, Shadi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title salt, (C(5)H(12)NO)(6)[PMo(12)O(40)](2)·5C(5)H(11)NO, there are two independent α-Keggin-type [PMo(12)O(40)](3−) polyoxidoanions, which show characteristic features with respect to bond lengths and angles. One of the [CH(3)CH(2)C(=OH)N(CH(3))(2)](+) cations is hydrogen bonded to the neighboring polyoxidoanion through a C=O—H⋯O(bridge) hydrogen bond. The organic mol­ecules and the remaining organic cations form [(C(5)H(11)NO)(2)H](+) mol­ecule–cation pairs, two of which lie about inversion centers, through O—H⋯O hydrogen bonds. International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435631/ /pubmed/22969504 http://dx.doi.org/10.1107/S1600536812036677 Text en © Raissi Shabari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Derakhshan Rad, Shadi
Hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) N,N-dimethyl­propionamide penta­solvate
title Hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) N,N-dimethyl­propionamide penta­solvate
title_full Hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) N,N-dimethyl­propionamide penta­solvate
title_fullStr Hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) N,N-dimethyl­propionamide penta­solvate
title_full_unstemmed Hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) N,N-dimethyl­propionamide penta­solvate
title_short Hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) N,N-dimethyl­propionamide penta­solvate
title_sort hexa­kis­{[1-(dimethyl­amino)­propyl­idene]oxidanium} bis­(dodeca­molybdo­phosphate) n,n-dimethyl­propionamide penta­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435631/
https://www.ncbi.nlm.nih.gov/pubmed/22969504
http://dx.doi.org/10.1107/S1600536812036677
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AT derakhshanradshadi hexakis1dimethylaminopropylideneoxidaniumbisdodecamolybdophosphatenndimethylpropionamidepentasolvate

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