cis-Dichloridobis[tris­(4-chloro­phen­yl)phosphane-κP]platinum(II) acetonitrile monosolvate

The title compound, [PtCl(2)(C(18)H(12)Cl(3)P)(2)]·C(2)H(3)N, packs as monomeric units with a square-planar geometry around the Pt(II) atom. The two tris­(4-chloro­phen­yl)phosphane ligands are coordinated in a cis orientation, with P—Pt—P and Cl—Pt—Cl angles of 99.36 (2) and 88.02 (2)°, respectivel...

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Detalles Bibliográficos
Autores principales: Meijboom, Reinout, Kirsten, Leo, Mbhele, Thapelo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435633/
https://www.ncbi.nlm.nih.gov/pubmed/22969506
http://dx.doi.org/10.1107/S1600536812037166
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author Meijboom, Reinout
Kirsten, Leo
Mbhele, Thapelo
author_facet Meijboom, Reinout
Kirsten, Leo
Mbhele, Thapelo
author_sort Meijboom, Reinout
collection PubMed
description The title compound, [PtCl(2)(C(18)H(12)Cl(3)P)(2)]·C(2)H(3)N, packs as monomeric units with a square-planar geometry around the Pt(II) atom. The two tris­(4-chloro­phen­yl)phosphane ligands are coordinated in a cis orientation, with P—Pt—P and Cl—Pt—Cl angles of 99.36 (2) and 88.02 (2)°, respectively. In the crystal, C—H⋯N inter­actions are observed between the phenyl rings and the acetonitrile solvent mol­ecules.
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spelling pubmed-34356332012-09-11 cis-Dichloridobis[tris­(4-chloro­phen­yl)phosphane-κP]platinum(II) acetonitrile monosolvate Meijboom, Reinout Kirsten, Leo Mbhele, Thapelo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PtCl(2)(C(18)H(12)Cl(3)P)(2)]·C(2)H(3)N, packs as monomeric units with a square-planar geometry around the Pt(II) atom. The two tris­(4-chloro­phen­yl)phosphane ligands are coordinated in a cis orientation, with P—Pt—P and Cl—Pt—Cl angles of 99.36 (2) and 88.02 (2)°, respectively. In the crystal, C—H⋯N inter­actions are observed between the phenyl rings and the acetonitrile solvent mol­ecules. International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435633/ /pubmed/22969506 http://dx.doi.org/10.1107/S1600536812037166 Text en © Meijboom et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meijboom, Reinout
Kirsten, Leo
Mbhele, Thapelo
cis-Dichloridobis[tris­(4-chloro­phen­yl)phosphane-κP]platinum(II) acetonitrile monosolvate
title cis-Dichloridobis[tris­(4-chloro­phen­yl)phosphane-κP]platinum(II) acetonitrile monosolvate
title_full cis-Dichloridobis[tris­(4-chloro­phen­yl)phosphane-κP]platinum(II) acetonitrile monosolvate
title_fullStr cis-Dichloridobis[tris­(4-chloro­phen­yl)phosphane-κP]platinum(II) acetonitrile monosolvate
title_full_unstemmed cis-Dichloridobis[tris­(4-chloro­phen­yl)phosphane-κP]platinum(II) acetonitrile monosolvate
title_short cis-Dichloridobis[tris­(4-chloro­phen­yl)phosphane-κP]platinum(II) acetonitrile monosolvate
title_sort cis-dichloridobis[tris­(4-chloro­phen­yl)phosphane-κp]platinum(ii) acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435633/
https://www.ncbi.nlm.nih.gov/pubmed/22969506
http://dx.doi.org/10.1107/S1600536812037166
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