5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile

The title 2-aza­bicyclo­[2.2.2]octa-2,5-diene derivative, C(14)H(18)N(4)O, crystallized out with two independent mol­ecules with similar conformations in the asymmetric unit. In each mol­ecule, the three six-membered rings adopt boat conformations. The mol­ecules exist in the enamine form. In the cr...

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Detalles Bibliográficos
Autores principales: Chantrapromma, Suchada, Suwunwong, Thitipone, Ruanwas, Pumsak, Boonnak, Nawong, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435638/
https://www.ncbi.nlm.nih.gov/pubmed/22969511
http://dx.doi.org/10.1107/S1600536812032990
Descripción
Sumario:The title 2-aza­bicyclo­[2.2.2]octa-2,5-diene derivative, C(14)H(18)N(4)O, crystallized out with two independent mol­ecules with similar conformations in the asymmetric unit. In each mol­ecule, the three six-membered rings adopt boat conformations. The mol­ecules exist in the enamine form. In the crystal, mol­ecules are linked by N—H⋯O and N—H⋯N hydrogen bonds into a two-dimensional network parallel to the ab plane.

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