5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile

The title 2-aza­bicyclo­[2.2.2]octa-2,5-diene derivative, C(14)H(18)N(4)O, crystallized out with two independent mol­ecules with similar conformations in the asymmetric unit. In each mol­ecule, the three six-membered rings adopt boat conformations. The mol­ecules exist in the enamine form. In the cr...

Descripción completa

Detalles Bibliográficos
Autores principales: Chantrapromma, Suchada, Suwunwong, Thitipone, Ruanwas, Pumsak, Boonnak, Nawong, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435638/
https://www.ncbi.nlm.nih.gov/pubmed/22969511
http://dx.doi.org/10.1107/S1600536812032990
_version_ 1782242558049517568
author Chantrapromma, Suchada
Suwunwong, Thitipone
Ruanwas, Pumsak
Boonnak, Nawong
Fun, Hoong-Kun
author_facet Chantrapromma, Suchada
Suwunwong, Thitipone
Ruanwas, Pumsak
Boonnak, Nawong
Fun, Hoong-Kun
author_sort Chantrapromma, Suchada
collection PubMed
description The title 2-aza­bicyclo­[2.2.2]octa-2,5-diene derivative, C(14)H(18)N(4)O, crystallized out with two independent mol­ecules with similar conformations in the asymmetric unit. In each mol­ecule, the three six-membered rings adopt boat conformations. The mol­ecules exist in the enamine form. In the crystal, mol­ecules are linked by N—H⋯O and N—H⋯N hydrogen bonds into a two-dimensional network parallel to the ab plane.
format Online
Article
Text
id pubmed-3435638
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34356382012-09-11 5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile Chantrapromma, Suchada Suwunwong, Thitipone Ruanwas, Pumsak Boonnak, Nawong Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title 2-aza­bicyclo­[2.2.2]octa-2,5-diene derivative, C(14)H(18)N(4)O, crystallized out with two independent mol­ecules with similar conformations in the asymmetric unit. In each mol­ecule, the three six-membered rings adopt boat conformations. The mol­ecules exist in the enamine form. In the crystal, mol­ecules are linked by N—H⋯O and N—H⋯N hydrogen bonds into a two-dimensional network parallel to the ab plane. International Union of Crystallography 2012-08-01 /pmc/articles/PMC3435638/ /pubmed/22969511 http://dx.doi.org/10.1107/S1600536812032990 Text en © Chantrapromma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chantrapromma, Suchada
Suwunwong, Thitipone
Ruanwas, Pumsak
Boonnak, Nawong
Fun, Hoong-Kun
5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile
title 5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile
title_full 5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile
title_fullStr 5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile
title_full_unstemmed 5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile
title_short 5-Amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile
title_sort 5-amino-3-eth­oxy-1,8,8-trimethyl-2-aza­bicyclo­[2.2.2]octa-2,5-diene-4,6-dicarbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435638/
https://www.ncbi.nlm.nih.gov/pubmed/22969511
http://dx.doi.org/10.1107/S1600536812032990
work_keys_str_mv AT chantraprommasuchada 5amino3ethoxy188trimethyl2azabicyclo222octa25diene46dicarbonitrile
AT suwunwongthitipone 5amino3ethoxy188trimethyl2azabicyclo222octa25diene46dicarbonitrile
AT ruanwaspumsak 5amino3ethoxy188trimethyl2azabicyclo222octa25diene46dicarbonitrile
AT boonnaknawong 5amino3ethoxy188trimethyl2azabicyclo222octa25diene46dicarbonitrile
AT funhoongkun 5amino3ethoxy188trimethyl2azabicyclo222octa25diene46dicarbonitrile

Ejemplares similares