2,3,5-Triphenyl-2H-tetra­zol-3-ium iodide

The asymmetric unit of the title mol­ecular salt, C(19)H(15)N(4) (+)·I(−), contains four 2,3,5-triphenyl-2H-tetra­zol-3-ium cations and five iodide anions, with two of the latter lying on crystallographic inversion centres. In each cation, the tetra­zole ring is essentially planar (r.m.s. deviations...

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Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Mostafa, Gamal A. E., Abunassif, Mohamed M., Abdel-Aziz, Hatem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435649/
https://www.ncbi.nlm.nih.gov/pubmed/22969522
http://dx.doi.org/10.1107/S1600536812033661
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author Fun, Hoong-Kun
Chia, Tze Shyang
Mostafa, Gamal A. E.
Abunassif, Mohamed M.
Abdel-Aziz, Hatem A.
author_facet Fun, Hoong-Kun
Chia, Tze Shyang
Mostafa, Gamal A. E.
Abunassif, Mohamed M.
Abdel-Aziz, Hatem A.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title mol­ecular salt, C(19)H(15)N(4) (+)·I(−), contains four 2,3,5-triphenyl-2H-tetra­zol-3-ium cations and five iodide anions, with two of the latter lying on crystallographic inversion centres. In each cation, the tetra­zole ring is essentially planar (r.m.s. deviations = 0.004–0.007 Å). The dihedral angles between the tetra­zole ring and its three attached benzene rings in the four independent cations are: 12.9 (4), 67.0 (4), 48.1 (4); 20.8 (4), 51.1 (4), 62.3 (4); 11.4 (4), 52.3 (4), 47.3 (4) and 6.0 (4), 85.7 (4), 43.5 (4)°. A C—H⋯I hydrogen bond and C—H⋯π inter­actions are observed in the crystal.
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spelling pubmed-34356492012-09-11 2,3,5-Triphenyl-2H-tetra­zol-3-ium iodide Fun, Hoong-Kun Chia, Tze Shyang Mostafa, Gamal A. E. Abunassif, Mohamed M. Abdel-Aziz, Hatem A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title mol­ecular salt, C(19)H(15)N(4) (+)·I(−), contains four 2,3,5-triphenyl-2H-tetra­zol-3-ium cations and five iodide anions, with two of the latter lying on crystallographic inversion centres. In each cation, the tetra­zole ring is essentially planar (r.m.s. deviations = 0.004–0.007 Å). The dihedral angles between the tetra­zole ring and its three attached benzene rings in the four independent cations are: 12.9 (4), 67.0 (4), 48.1 (4); 20.8 (4), 51.1 (4), 62.3 (4); 11.4 (4), 52.3 (4), 47.3 (4) and 6.0 (4), 85.7 (4), 43.5 (4)°. A C—H⋯I hydrogen bond and C—H⋯π inter­actions are observed in the crystal. International Union of Crystallography 2012-08-01 /pmc/articles/PMC3435649/ /pubmed/22969522 http://dx.doi.org/10.1107/S1600536812033661 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chia, Tze Shyang
Mostafa, Gamal A. E.
Abunassif, Mohamed M.
Abdel-Aziz, Hatem A.
2,3,5-Triphenyl-2H-tetra­zol-3-ium iodide
title 2,3,5-Triphenyl-2H-tetra­zol-3-ium iodide
title_full 2,3,5-Triphenyl-2H-tetra­zol-3-ium iodide
title_fullStr 2,3,5-Triphenyl-2H-tetra­zol-3-ium iodide
title_full_unstemmed 2,3,5-Triphenyl-2H-tetra­zol-3-ium iodide
title_short 2,3,5-Triphenyl-2H-tetra­zol-3-ium iodide
title_sort 2,3,5-triphenyl-2h-tetra­zol-3-ium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435649/
https://www.ncbi.nlm.nih.gov/pubmed/22969522
http://dx.doi.org/10.1107/S1600536812033661
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