2-Methyl-3-nitro-N-{(E)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline

In the title Schiff-base type compound, C(18)H(13)N(3)O(5), the central furan ring makes dihedral angles of 12.80 (7) and 51.43 (4)° with the terminal benzene rings. The dihedral angle between the benzene rings is 45.43 (3)°. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into layers paral...

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Autores principales: Pekdemir, Merve, Işık, Şamil, Gümüş, Sümeyye, Ağar, Erbil, Öztürk Yıldırım, Sema, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435658/
https://www.ncbi.nlm.nih.gov/pubmed/22969531
http://dx.doi.org/10.1107/S1600536812033818
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author Pekdemir, Merve
Işık, Şamil
Gümüş, Sümeyye
Ağar, Erbil
Öztürk Yıldırım, Sema
Butcher, Ray J.
author_facet Pekdemir, Merve
Işık, Şamil
Gümüş, Sümeyye
Ağar, Erbil
Öztürk Yıldırım, Sema
Butcher, Ray J.
author_sort Pekdemir, Merve
collection PubMed
description In the title Schiff-base type compound, C(18)H(13)N(3)O(5), the central furan ring makes dihedral angles of 12.80 (7) and 51.43 (4)° with the terminal benzene rings. The dihedral angle between the benzene rings is 45.43 (3)°. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into layers parallel to (010). In addition, there are π–π stacking inter­actions within the layer [centroid–centroid distance = 3.584 (1) Å] and between the layers [centroid–centroid distance 3.751 (1) Å].
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spelling pubmed-34356582012-09-11 2-Methyl-3-nitro-N-{(E)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline Pekdemir, Merve Işık, Şamil Gümüş, Sümeyye Ağar, Erbil Öztürk Yıldırım, Sema Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff-base type compound, C(18)H(13)N(3)O(5), the central furan ring makes dihedral angles of 12.80 (7) and 51.43 (4)° with the terminal benzene rings. The dihedral angle between the benzene rings is 45.43 (3)°. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into layers parallel to (010). In addition, there are π–π stacking inter­actions within the layer [centroid–centroid distance = 3.584 (1) Å] and between the layers [centroid–centroid distance 3.751 (1) Å]. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435658/ /pubmed/22969531 http://dx.doi.org/10.1107/S1600536812033818 Text en © Pekdemir et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pekdemir, Merve
Işık, Şamil
Gümüş, Sümeyye
Ağar, Erbil
Öztürk Yıldırım, Sema
Butcher, Ray J.
2-Methyl-3-nitro-N-{(E)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline
title 2-Methyl-3-nitro-N-{(E)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline
title_full 2-Methyl-3-nitro-N-{(E)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline
title_fullStr 2-Methyl-3-nitro-N-{(E)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline
title_full_unstemmed 2-Methyl-3-nitro-N-{(E)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline
title_short 2-Methyl-3-nitro-N-{(E)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline
title_sort 2-methyl-3-nitro-n-{(e)-[5-(4-nitro­phen­yl)furan-2-yl]methyl­idene}aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435658/
https://www.ncbi.nlm.nih.gov/pubmed/22969531
http://dx.doi.org/10.1107/S1600536812033818
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