Cargando…
4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol
The asymmetric unit of the title compound, C(28)H(22)Br(2)N(2)O(2)S(2), comprises half of a Schiff base ligand, the whole molecule being generated by a crystallographic inversion center located at the mid-point of the C—C bond of the central methylene segment. Intramolecular O—H⋯N and O—H⋯S hydro...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435662/ https://www.ncbi.nlm.nih.gov/pubmed/22969535 http://dx.doi.org/10.1107/S1600536812034071 |
_version_ | 1782242563826122752 |
---|---|
author | Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz |
author_facet | Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz |
author_sort | Kargar, Hadi |
collection | PubMed |
description | The asymmetric unit of the title compound, C(28)H(22)Br(2)N(2)O(2)S(2), comprises half of a Schiff base ligand, the whole molecule being generated by a crystallographic inversion center located at the mid-point of the C—C bond of the central methylene segment. Intramolecular O—H⋯N and O—H⋯S hydrogen bonds make S(6) and S(5) ring motifs, respectively. In the crystal, there are no significant intermolecular interactions. |
format | Online Article Text |
id | pubmed-3435662 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34356622012-09-11 4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(28)H(22)Br(2)N(2)O(2)S(2), comprises half of a Schiff base ligand, the whole molecule being generated by a crystallographic inversion center located at the mid-point of the C—C bond of the central methylene segment. Intramolecular O—H⋯N and O—H⋯S hydrogen bonds make S(6) and S(5) ring motifs, respectively. In the crystal, there are no significant intermolecular interactions. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435662/ /pubmed/22969535 http://dx.doi.org/10.1107/S1600536812034071 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz 4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol |
title | 4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol |
title_full | 4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol |
title_fullStr | 4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol |
title_full_unstemmed | 4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol |
title_short | 4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol |
title_sort | 4-bromo-2-[(e)-(2-{2-[(2-{[(e)-5-bromo-2-hydroxybenzylidene]amino}phenyl)sulfanyl]ethylsulfanyl}phenyl)iminomethyl]phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435662/ https://www.ncbi.nlm.nih.gov/pubmed/22969535 http://dx.doi.org/10.1107/S1600536812034071 |
work_keys_str_mv | AT kargarhadi 4bromo2e222e5bromo2hydroxybenzylideneaminophenylsulfanylethylsulfanylphenyliminomethylphenol AT kiareza 4bromo2e222e5bromo2hydroxybenzylideneaminophenylsulfanylethylsulfanylphenyliminomethylphenol AT tahirmuhammadnawaz 4bromo2e222e5bromo2hydroxybenzylideneaminophenylsulfanylethylsulfanylphenyliminomethylphenol |