2-Nitro-N-phenyl­benzene­sulfonamide

In the title compound, C(12)H(10)N(2)O(4)S, the conformation of the N—H bond in the –SO(2)—NH– fragment is syn to the ortho-nitro group in the sulfonyl­benzene ring. The mol­ecule is twisted at the S—N bond, the C—N—S—C torsion angle being −72.83 (15)°. The dihedral angle between the benzene rings i...

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Detalles Bibliográficos
Autores principales: Chaithanya, U., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435678/
https://www.ncbi.nlm.nih.gov/pubmed/22969549
http://dx.doi.org/10.1107/S1600536812034265
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author Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
author_facet Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
author_sort Chaithanya, U.
collection PubMed
description In the title compound, C(12)H(10)N(2)O(4)S, the conformation of the N—H bond in the –SO(2)—NH– fragment is syn to the ortho-nitro group in the sulfonyl­benzene ring. The mol­ecule is twisted at the S—N bond, the C—N—S—C torsion angle being −72.83 (15)°. The dihedral angle between the benzene rings is 59.55 (7)°. The amide H atom and the nitro group O atom form an intra­molecular hydrogen bond, generating an S(7) motif. In the crystal, C—H⋯O hydrogen-bond inter­actions link the mol­ecules into S (2) (2)(10) networks.
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spelling pubmed-34356782012-09-11 2-Nitro-N-phenyl­benzene­sulfonamide Chaithanya, U. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(10)N(2)O(4)S, the conformation of the N—H bond in the –SO(2)—NH– fragment is syn to the ortho-nitro group in the sulfonyl­benzene ring. The mol­ecule is twisted at the S—N bond, the C—N—S—C torsion angle being −72.83 (15)°. The dihedral angle between the benzene rings is 59.55 (7)°. The amide H atom and the nitro group O atom form an intra­molecular hydrogen bond, generating an S(7) motif. In the crystal, C—H⋯O hydrogen-bond inter­actions link the mol­ecules into S (2) (2)(10) networks. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435678/ /pubmed/22969549 http://dx.doi.org/10.1107/S1600536812034265 Text en © Chaithanya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
2-Nitro-N-phenyl­benzene­sulfonamide
title 2-Nitro-N-phenyl­benzene­sulfonamide
title_full 2-Nitro-N-phenyl­benzene­sulfonamide
title_fullStr 2-Nitro-N-phenyl­benzene­sulfonamide
title_full_unstemmed 2-Nitro-N-phenyl­benzene­sulfonamide
title_short 2-Nitro-N-phenyl­benzene­sulfonamide
title_sort 2-nitro-n-phenyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435678/
https://www.ncbi.nlm.nih.gov/pubmed/22969549
http://dx.doi.org/10.1107/S1600536812034265
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