2,2-Diphenyl-N-(2,4,5-trichloro­phen­yl)acetamide

The asymmetric unit of the title compound, C(20)H(14)Cl(3)NO, consists of two independent mol­ecules. In one mol­ecule, the chlorinated benzene ring forms dihedral angles of 12.00 (9) and 77.04 (9)° with the phenyl rings. The dihedral angle between the phenyl rings is 80.37 (10)°. The corresponding...

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Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Nayak, Prakash S., Narayana, B., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435685/
https://www.ncbi.nlm.nih.gov/pubmed/22969556
http://dx.doi.org/10.1107/S160053681203440X
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author Fun, Hoong-Kun
Quah, Ching Kheng
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
author_facet Fun, Hoong-Kun
Quah, Ching Kheng
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(20)H(14)Cl(3)NO, consists of two independent mol­ecules. In one mol­ecule, the chlorinated benzene ring forms dihedral angles of 12.00 (9) and 77.04 (9)° with the phenyl rings. The dihedral angle between the phenyl rings is 80.37 (10)°. The corresponding dihedral angles for the other mol­ecule are 26.34 (10), 62.98 (10) and 88.47 (11)°, respectively. One of the mol­ecules features an intra­molecular C—H⋯O hydrogen bond, which forms an S(6) ring motif. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into [100] chains. The chains are further linked by C—H⋯O and C—H⋯Cl hydrogen bonds into a three-dimensional network.
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spelling pubmed-34356852012-09-11 2,2-Diphenyl-N-(2,4,5-trichloro­phen­yl)acetamide Fun, Hoong-Kun Quah, Ching Kheng Nayak, Prakash S. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(20)H(14)Cl(3)NO, consists of two independent mol­ecules. In one mol­ecule, the chlorinated benzene ring forms dihedral angles of 12.00 (9) and 77.04 (9)° with the phenyl rings. The dihedral angle between the phenyl rings is 80.37 (10)°. The corresponding dihedral angles for the other mol­ecule are 26.34 (10), 62.98 (10) and 88.47 (11)°, respectively. One of the mol­ecules features an intra­molecular C—H⋯O hydrogen bond, which forms an S(6) ring motif. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into [100] chains. The chains are further linked by C—H⋯O and C—H⋯Cl hydrogen bonds into a three-dimensional network. International Union of Crystallography 2012-08-08 /pmc/articles/PMC3435685/ /pubmed/22969556 http://dx.doi.org/10.1107/S160053681203440X Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Quah, Ching Kheng
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
2,2-Diphenyl-N-(2,4,5-trichloro­phen­yl)acetamide
title 2,2-Diphenyl-N-(2,4,5-trichloro­phen­yl)acetamide
title_full 2,2-Diphenyl-N-(2,4,5-trichloro­phen­yl)acetamide
title_fullStr 2,2-Diphenyl-N-(2,4,5-trichloro­phen­yl)acetamide
title_full_unstemmed 2,2-Diphenyl-N-(2,4,5-trichloro­phen­yl)acetamide
title_short 2,2-Diphenyl-N-(2,4,5-trichloro­phen­yl)acetamide
title_sort 2,2-diphenyl-n-(2,4,5-trichloro­phen­yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435685/
https://www.ncbi.nlm.nih.gov/pubmed/22969556
http://dx.doi.org/10.1107/S160053681203440X
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