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(Z)-3-Methoxy-N-[(5-nitrothiophen-2-yl)methylidene]aniline
In the title compound, C(12)H(10)N(2)O(3)S, the dihedral angle between the benzene and thiophene rings is 43.17 (4)°. The crystal structure is devoid of any hydrogen-bonding interactions. However, π–π interactions between the benzene and thiophene rings [distance between ring centroids = 3.6850 ...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435696/ https://www.ncbi.nlm.nih.gov/pubmed/22969567 http://dx.doi.org/10.1107/S1600536812033120 |
Sumario: | In the title compound, C(12)H(10)N(2)O(3)S, the dihedral angle between the benzene and thiophene rings is 43.17 (4)°. The crystal structure is devoid of any hydrogen-bonding interactions. However, π–π interactions between the benzene and thiophene rings [distance between ring centroids = 3.6850 (11) Å] stack the molecules along the a axis. The absolute structure could not be determined as the crystal studied was a racemic twin with a BASF parameter of 0.31 (6). |
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