(Z)-3-Meth­oxy-N-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline

In the title compound, C(12)H(10)N(2)O(3)S, the dihedral angle between the benzene and thio­phene rings is 43.17 (4)°. The crystal structure is devoid of any hydrogen-bonding inter­actions. However, π–π inter­actions between the benzene and thio­phene rings [distance between ring centroids = 3.6850 ...

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Detalles Bibliográficos
Autores principales: Akbal, Tufan, Ağar, Erbil, Erdönmez, Ahmet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435696/
https://www.ncbi.nlm.nih.gov/pubmed/22969567
http://dx.doi.org/10.1107/S1600536812033120
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author Akbal, Tufan
Ağar, Erbil
Erdönmez, Ahmet
author_facet Akbal, Tufan
Ağar, Erbil
Erdönmez, Ahmet
author_sort Akbal, Tufan
collection PubMed
description In the title compound, C(12)H(10)N(2)O(3)S, the dihedral angle between the benzene and thio­phene rings is 43.17 (4)°. The crystal structure is devoid of any hydrogen-bonding inter­actions. However, π–π inter­actions between the benzene and thio­phene rings [distance between ring centroids = 3.6850 (11) Å] stack the mol­ecules along the a axis. The absolute structure could not be determined as the crystal studied was a racemic twin with a BASF parameter of 0.31 (6).
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spelling pubmed-34356962012-09-11 (Z)-3-Meth­oxy-N-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline Akbal, Tufan Ağar, Erbil Erdönmez, Ahmet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(10)N(2)O(3)S, the dihedral angle between the benzene and thio­phene rings is 43.17 (4)°. The crystal structure is devoid of any hydrogen-bonding inter­actions. However, π–π inter­actions between the benzene and thio­phene rings [distance between ring centroids = 3.6850 (11) Å] stack the mol­ecules along the a axis. The absolute structure could not be determined as the crystal studied was a racemic twin with a BASF parameter of 0.31 (6). International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435696/ /pubmed/22969567 http://dx.doi.org/10.1107/S1600536812033120 Text en © Akbal et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akbal, Tufan
Ağar, Erbil
Erdönmez, Ahmet
(Z)-3-Meth­oxy-N-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title (Z)-3-Meth­oxy-N-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_full (Z)-3-Meth­oxy-N-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_fullStr (Z)-3-Meth­oxy-N-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_full_unstemmed (Z)-3-Meth­oxy-N-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_short (Z)-3-Meth­oxy-N-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_sort (z)-3-meth­oxy-n-[(5-nitro­thio­phen-2-yl)methyl­idene]aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435696/
https://www.ncbi.nlm.nih.gov/pubmed/22969567
http://dx.doi.org/10.1107/S1600536812033120
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