(E)-1-(2,4-Dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine

In the asymmetric unit of the title compound, C(14)H(11)N(5)O(6), there are three crystallographically independent mol­ecules with similar conformations but some differences in bond angles. The mol­ecules are slightly twisted with the dihedral angles between the benzene rings being 10.02 (14), 8.41 ...

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Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Nilwanna, Boonlerd, Kobkeatthawin, Thawanrat, Boonnak, Nawong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435706/
https://www.ncbi.nlm.nih.gov/pubmed/22969577
http://dx.doi.org/10.1107/S1600536812034812
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author Fun, Hoong-Kun
Chantrapromma, Suchada
Nilwanna, Boonlerd
Kobkeatthawin, Thawanrat
Boonnak, Nawong
author_facet Fun, Hoong-Kun
Chantrapromma, Suchada
Nilwanna, Boonlerd
Kobkeatthawin, Thawanrat
Boonnak, Nawong
author_sort Fun, Hoong-Kun
collection PubMed
description In the asymmetric unit of the title compound, C(14)H(11)N(5)O(6), there are three crystallographically independent mol­ecules with similar conformations but some differences in bond angles. The mol­ecules are slightly twisted with the dihedral angles between the benzene rings being 10.02 (14), 8.41 (15) and 1.40 (14)°. In each mol­ecule, an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions into a three-dimensional network. π–π inter­actions with centroid–centroid distances of 3.5635 (17)–3.8273 (18) Å are observed.
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spelling pubmed-34357062012-09-11 (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine Fun, Hoong-Kun Chantrapromma, Suchada Nilwanna, Boonlerd Kobkeatthawin, Thawanrat Boonnak, Nawong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, C(14)H(11)N(5)O(6), there are three crystallographically independent mol­ecules with similar conformations but some differences in bond angles. The mol­ecules are slightly twisted with the dihedral angles between the benzene rings being 10.02 (14), 8.41 (15) and 1.40 (14)°. In each mol­ecule, an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions into a three-dimensional network. π–π inter­actions with centroid–centroid distances of 3.5635 (17)–3.8273 (18) Å are observed. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435706/ /pubmed/22969577 http://dx.doi.org/10.1107/S1600536812034812 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chantrapromma, Suchada
Nilwanna, Boonlerd
Kobkeatthawin, Thawanrat
Boonnak, Nawong
(E)-1-(2,4-Dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine
title (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine
title_full (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine
title_fullStr (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine
title_full_unstemmed (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine
title_short (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine
title_sort (e)-1-(2,4-dinitro­phen­yl)-2-[1-(3-nitro­phen­yl)ethyl­idene]hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435706/
https://www.ncbi.nlm.nih.gov/pubmed/22969577
http://dx.doi.org/10.1107/S1600536812034812
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