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2-Hy­droxy-N′-methyl­benzohydrazide

In the title mol­ecule, C(8)H(10)N(2)O(2), there is an intra­molecular hydrogen bond involving the hy­droxy group and the O atom of the carbonyl group. The dihedral angle between the benzene ring and the amide fragment is 87.16 (10)°. The C—N—N—C torsion angle is 88.87 (18)°. In the crystal, N—H⋯N a...

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Detalles Bibliográficos
Autor principal: Zhang, Xinwen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435707/
https://www.ncbi.nlm.nih.gov/pubmed/22969578
http://dx.doi.org/10.1107/S160053681203468X
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author Zhang, Xinwen
author_facet Zhang, Xinwen
author_sort Zhang, Xinwen
collection PubMed
description In the title mol­ecule, C(8)H(10)N(2)O(2), there is an intra­molecular hydrogen bond involving the hy­droxy group and the O atom of the carbonyl group. The dihedral angle between the benzene ring and the amide fragment is 87.16 (10)°. The C—N—N—C torsion angle is 88.87 (18)°. In the crystal, N—H⋯N and N—H⋯O hydrogen bonds connect mol­ecules into chains along [100]. In addition, there is a weak C—H⋯π inter­action.
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spelling pubmed-34357072012-09-11 2-Hy­droxy-N′-methyl­benzohydrazide Zhang, Xinwen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(8)H(10)N(2)O(2), there is an intra­molecular hydrogen bond involving the hy­droxy group and the O atom of the carbonyl group. The dihedral angle between the benzene ring and the amide fragment is 87.16 (10)°. The C—N—N—C torsion angle is 88.87 (18)°. In the crystal, N—H⋯N and N—H⋯O hydrogen bonds connect mol­ecules into chains along [100]. In addition, there is a weak C—H⋯π inter­action. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435707/ /pubmed/22969578 http://dx.doi.org/10.1107/S160053681203468X Text en © Xinwen Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Xinwen
2-Hy­droxy-N′-methyl­benzohydrazide
title 2-Hy­droxy-N′-methyl­benzohydrazide
title_full 2-Hy­droxy-N′-methyl­benzohydrazide
title_fullStr 2-Hy­droxy-N′-methyl­benzohydrazide
title_full_unstemmed 2-Hy­droxy-N′-methyl­benzohydrazide
title_short 2-Hy­droxy-N′-methyl­benzohydrazide
title_sort 2-hy­droxy-n′-methyl­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435707/
https://www.ncbi.nlm.nih.gov/pubmed/22969578
http://dx.doi.org/10.1107/S160053681203468X
work_keys_str_mv AT zhangxinwen 2hydroxynmethylbenzohydrazide