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2-Hydroxy-N′-methylbenzohydrazide
In the title molecule, C(8)H(10)N(2)O(2), there is an intramolecular hydrogen bond involving the hydroxy group and the O atom of the carbonyl group. The dihedral angle between the benzene ring and the amide fragment is 87.16 (10)°. The C—N—N—C torsion angle is 88.87 (18)°. In the crystal, N—H⋯N a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435707/ https://www.ncbi.nlm.nih.gov/pubmed/22969578 http://dx.doi.org/10.1107/S160053681203468X |
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author | Zhang, Xinwen |
author_facet | Zhang, Xinwen |
author_sort | Zhang, Xinwen |
collection | PubMed |
description | In the title molecule, C(8)H(10)N(2)O(2), there is an intramolecular hydrogen bond involving the hydroxy group and the O atom of the carbonyl group. The dihedral angle between the benzene ring and the amide fragment is 87.16 (10)°. The C—N—N—C torsion angle is 88.87 (18)°. In the crystal, N—H⋯N and N—H⋯O hydrogen bonds connect molecules into chains along [100]. In addition, there is a weak C—H⋯π interaction. |
format | Online Article Text |
id | pubmed-3435707 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34357072012-09-11 2-Hydroxy-N′-methylbenzohydrazide Zhang, Xinwen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(8)H(10)N(2)O(2), there is an intramolecular hydrogen bond involving the hydroxy group and the O atom of the carbonyl group. The dihedral angle between the benzene ring and the amide fragment is 87.16 (10)°. The C—N—N—C torsion angle is 88.87 (18)°. In the crystal, N—H⋯N and N—H⋯O hydrogen bonds connect molecules into chains along [100]. In addition, there is a weak C—H⋯π interaction. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435707/ /pubmed/22969578 http://dx.doi.org/10.1107/S160053681203468X Text en © Xinwen Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Xinwen 2-Hydroxy-N′-methylbenzohydrazide |
title | 2-Hydroxy-N′-methylbenzohydrazide |
title_full | 2-Hydroxy-N′-methylbenzohydrazide |
title_fullStr | 2-Hydroxy-N′-methylbenzohydrazide |
title_full_unstemmed | 2-Hydroxy-N′-methylbenzohydrazide |
title_short | 2-Hydroxy-N′-methylbenzohydrazide |
title_sort | 2-hydroxy-n′-methylbenzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435707/ https://www.ncbi.nlm.nih.gov/pubmed/22969578 http://dx.doi.org/10.1107/S160053681203468X |
work_keys_str_mv | AT zhangxinwen 2hydroxynmethylbenzohydrazide |