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1-[(4-Chloro­phen­yl)(phen­yl)meth­yl]piperazine-1,4-diium bis­(trichloro­acetate)–trichloro­acetic acid (1/1)

In the title salt adduct, C(17)H(21)ClN(2) (2+)·2C(2)Cl(3)O(2) (−)·C(2)HCl(3)O(2), the Cl atom of the dication is disordered over two positions in a 0.915 (3):0.085 (3) ratio. The Cl atoms in the trichloroacetate anions and trichloroacetic acid molecule are also disordered, with refined site-occupat...

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Detalles Bibliográficos
Autores principales: Song, Yanxi, Chidan Kumar, C. S., Akkurt, Mehmet, Chandraju, S., Li, Hongqi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435716/
https://www.ncbi.nlm.nih.gov/pubmed/22969587
http://dx.doi.org/10.1107/S1600536812034794
Descripción
Sumario:In the title salt adduct, C(17)H(21)ClN(2) (2+)·2C(2)Cl(3)O(2) (−)·C(2)HCl(3)O(2), the Cl atom of the dication is disordered over two positions in a 0.915 (3):0.085 (3) ratio. The Cl atoms in the trichloroacetate anions and trichloroacetic acid molecule are also disordered, with refined site-occupation factors of 0.59 (3):0.41 (3), 0.503 (12):0.417 (12) and 0.653 (12):0.347 (12). The piperazine ring adopts a chair conformation, with puckering parameters Q (T) = 0.587 (3) Å, θ = 2.6 (2) and Φ 334 (6)°. In the crystal, neighbouring mol­ecules are linked by N—H⋯O, O—H⋯O, N—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds, forming a three-dimensional network.