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2-Meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol

In the title compound, C(17)H(19)NO(3), the dihedral angle between the benzene rings is 68.0 (1)°. The C—O—C—C torsion angle of the atoms joining these rings is 179.7 (2)°. The atoms of the methanol group were refined as disordered over two sets of sites with fixed occupancies of 0.86 and 0.14. The...

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Autores principales: Kant, Rajni, Gupta, Vivek K., Kapoor, Kamini, Shripanavar, Chetan S., Banerjee, Kaushik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435717/
https://www.ncbi.nlm.nih.gov/pubmed/22969588
http://dx.doi.org/10.1107/S160053681203499X
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author Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
author_facet Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
author_sort Kant, Rajni
collection PubMed
description In the title compound, C(17)H(19)NO(3), the dihedral angle between the benzene rings is 68.0 (1)°. The C—O—C—C torsion angle of the atoms joining these rings is 179.7 (2)°. The atoms of the methanol group were refined as disordered over two sets of sites with fixed occupancies of 0.86 and 0.14. The H atoms of the hy­droxy group in the major component are disordered over a further two sets of sites with equal occupancies. This is a necessary arrangement to allow for hydrogen bonding without unrealistic H⋯H contacts. In the crystal, O—H⋯N and O—H⋯O hydrogen bonds connect mol­ecules into chains along [001].
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spelling pubmed-34357172012-09-11 2-Meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Shripanavar, Chetan S. Banerjee, Kaushik Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(19)NO(3), the dihedral angle between the benzene rings is 68.0 (1)°. The C—O—C—C torsion angle of the atoms joining these rings is 179.7 (2)°. The atoms of the methanol group were refined as disordered over two sets of sites with fixed occupancies of 0.86 and 0.14. The H atoms of the hy­droxy group in the major component are disordered over a further two sets of sites with equal occupancies. This is a necessary arrangement to allow for hydrogen bonding without unrealistic H⋯H contacts. In the crystal, O—H⋯N and O—H⋯O hydrogen bonds connect mol­ecules into chains along [001]. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435717/ /pubmed/22969588 http://dx.doi.org/10.1107/S160053681203499X Text en © Kant et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
2-Meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol
title 2-Meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol
title_full 2-Meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol
title_fullStr 2-Meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol
title_full_unstemmed 2-Meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol
title_short 2-Meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol
title_sort 2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}ethanol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435717/
https://www.ncbi.nlm.nih.gov/pubmed/22969588
http://dx.doi.org/10.1107/S160053681203499X
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