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2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol
In the title compound, C(17)H(19)NO(3), the dihedral angle between the benzene rings is 68.0 (1)°. The C—O—C—C torsion angle of the atoms joining these rings is 179.7 (2)°. The atoms of the methanol group were refined as disordered over two sets of sites with fixed occupancies of 0.86 and 0.14. The...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435717/ https://www.ncbi.nlm.nih.gov/pubmed/22969588 http://dx.doi.org/10.1107/S160053681203499X |
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author | Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Shripanavar, Chetan S. Banerjee, Kaushik |
author_facet | Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Shripanavar, Chetan S. Banerjee, Kaushik |
author_sort | Kant, Rajni |
collection | PubMed |
description | In the title compound, C(17)H(19)NO(3), the dihedral angle between the benzene rings is 68.0 (1)°. The C—O—C—C torsion angle of the atoms joining these rings is 179.7 (2)°. The atoms of the methanol group were refined as disordered over two sets of sites with fixed occupancies of 0.86 and 0.14. The H atoms of the hydroxy group in the major component are disordered over a further two sets of sites with equal occupancies. This is a necessary arrangement to allow for hydrogen bonding without unrealistic H⋯H contacts. In the crystal, O—H⋯N and O—H⋯O hydrogen bonds connect molecules into chains along [001]. |
format | Online Article Text |
id | pubmed-3435717 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34357172012-09-11 2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Shripanavar, Chetan S. Banerjee, Kaushik Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(19)NO(3), the dihedral angle between the benzene rings is 68.0 (1)°. The C—O—C—C torsion angle of the atoms joining these rings is 179.7 (2)°. The atoms of the methanol group were refined as disordered over two sets of sites with fixed occupancies of 0.86 and 0.14. The H atoms of the hydroxy group in the major component are disordered over a further two sets of sites with equal occupancies. This is a necessary arrangement to allow for hydrogen bonding without unrealistic H⋯H contacts. In the crystal, O—H⋯N and O—H⋯O hydrogen bonds connect molecules into chains along [001]. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435717/ /pubmed/22969588 http://dx.doi.org/10.1107/S160053681203499X Text en © Kant et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Shripanavar, Chetan S. Banerjee, Kaushik 2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol |
title | 2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol |
title_full | 2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol |
title_fullStr | 2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol |
title_full_unstemmed | 2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol |
title_short | 2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol |
title_sort | 2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435717/ https://www.ncbi.nlm.nih.gov/pubmed/22969588 http://dx.doi.org/10.1107/S160053681203499X |
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