N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine

In the title mol­ecule, C(9)H(6)Cl(2)N(2)S, the mean planes of the benzene and thia­zole rings make a dihedral angle of 54.18 (8)°. In the crystal, mol­ecules are joined into dimers with an R (2) (2)(8) ring motif by pairs of N—H⋯N hydrogen bonds. These dimers are linked by C—H⋯Cl inter­actions into...

Descripción completa

Detalles Bibliográficos
Autores principales: Babar, Ayesha, Munawar, Munawar Ali, Tahir, M. Nawaz, Ullah, Fateh, Tariq, Muhammad Ilyas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435722/
https://www.ncbi.nlm.nih.gov/pubmed/22969593
http://dx.doi.org/10.1107/S1600536812035301
Descripción
Sumario:In the title mol­ecule, C(9)H(6)Cl(2)N(2)S, the mean planes of the benzene and thia­zole rings make a dihedral angle of 54.18 (8)°. In the crystal, mol­ecules are joined into dimers with an R (2) (2)(8) ring motif by pairs of N—H⋯N hydrogen bonds. These dimers are linked by C—H⋯Cl inter­actions into layers parallel to (011). The thia­zole rings form columns along the c-axis direction, with a centroid–centroid separation of 3.8581 (9) Å, indicating π–π inter­actions. An intra­molecular C—H⋯S contact also occurs.

Ejemplares similares