N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine

In the title mol­ecule, C(9)H(6)Cl(2)N(2)S, the mean planes of the benzene and thia­zole rings make a dihedral angle of 54.18 (8)°. In the crystal, mol­ecules are joined into dimers with an R (2) (2)(8) ring motif by pairs of N—H⋯N hydrogen bonds. These dimers are linked by C—H⋯Cl inter­actions into...

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Detalles Bibliográficos
Autores principales: Babar, Ayesha, Munawar, Munawar Ali, Tahir, M. Nawaz, Ullah, Fateh, Tariq, Muhammad Ilyas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435722/
https://www.ncbi.nlm.nih.gov/pubmed/22969593
http://dx.doi.org/10.1107/S1600536812035301
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author Babar, Ayesha
Munawar, Munawar Ali
Tahir, M. Nawaz
Ullah, Fateh
Tariq, Muhammad Ilyas
author_facet Babar, Ayesha
Munawar, Munawar Ali
Tahir, M. Nawaz
Ullah, Fateh
Tariq, Muhammad Ilyas
author_sort Babar, Ayesha
collection PubMed
description In the title mol­ecule, C(9)H(6)Cl(2)N(2)S, the mean planes of the benzene and thia­zole rings make a dihedral angle of 54.18 (8)°. In the crystal, mol­ecules are joined into dimers with an R (2) (2)(8) ring motif by pairs of N—H⋯N hydrogen bonds. These dimers are linked by C—H⋯Cl inter­actions into layers parallel to (011). The thia­zole rings form columns along the c-axis direction, with a centroid–centroid separation of 3.8581 (9) Å, indicating π–π inter­actions. An intra­molecular C—H⋯S contact also occurs.
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spelling pubmed-34357222012-09-11 N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine Babar, Ayesha Munawar, Munawar Ali Tahir, M. Nawaz Ullah, Fateh Tariq, Muhammad Ilyas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(9)H(6)Cl(2)N(2)S, the mean planes of the benzene and thia­zole rings make a dihedral angle of 54.18 (8)°. In the crystal, mol­ecules are joined into dimers with an R (2) (2)(8) ring motif by pairs of N—H⋯N hydrogen bonds. These dimers are linked by C—H⋯Cl inter­actions into layers parallel to (011). The thia­zole rings form columns along the c-axis direction, with a centroid–centroid separation of 3.8581 (9) Å, indicating π–π inter­actions. An intra­molecular C—H⋯S contact also occurs. International Union of Crystallography 2012-08-15 /pmc/articles/PMC3435722/ /pubmed/22969593 http://dx.doi.org/10.1107/S1600536812035301 Text en © Babar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Babar, Ayesha
Munawar, Munawar Ali
Tahir, M. Nawaz
Ullah, Fateh
Tariq, Muhammad Ilyas
N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine
title N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine
title_full N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine
title_fullStr N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine
title_full_unstemmed N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine
title_short N-(2,4-Dichloro­phen­yl)-1,3-thia­zol-2-amine
title_sort n-(2,4-dichloro­phen­yl)-1,3-thia­zol-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435722/
https://www.ncbi.nlm.nih.gov/pubmed/22969593
http://dx.doi.org/10.1107/S1600536812035301
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AT tariqmuhammadilyas n24dichlorophenyl13thiazol2amine

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