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N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate

The title compound, C(13)H(10)FN(3)O·H(2)O, exists in the E conformation with respect to the azomethane C=N double bond. The mol­ecule is close to planar with a maximum deviation of 0.286 (2) Å. The pyridine ring is essentially coplanar with the central C(= O)N(2)C unit [dihedral angle = 2.02 (3)°]...

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Detalles Bibliográficos
Autores principales: Nair, Yamuna, Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435726/
https://www.ncbi.nlm.nih.gov/pubmed/22969597
http://dx.doi.org/10.1107/S1600536812035179
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author Nair, Yamuna
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Nair, Yamuna
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Nair, Yamuna
collection PubMed
description The title compound, C(13)H(10)FN(3)O·H(2)O, exists in the E conformation with respect to the azomethane C=N double bond. The mol­ecule is close to planar with a maximum deviation of 0.286 (2) Å. The pyridine ring is essentially coplanar with the central C(= O)N(2)C unit [dihedral angle = 2.02 (3)°] and the phenyl ring exhibits a dihedral angle of 14.41 (10)° with respect to the central unit. The crystal structure features O—H⋯N, N—H⋯O and O—H⋯O hydrogen-bond inter­actions between the solvent water and the benzohydrazide mol­ecules, as well as C—H⋯O hydrogen bonds and C—F⋯π [3.0833 (18) Å] inter­actions.
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spelling pubmed-34357262012-09-11 N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate Nair, Yamuna Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(10)FN(3)O·H(2)O, exists in the E conformation with respect to the azomethane C=N double bond. The mol­ecule is close to planar with a maximum deviation of 0.286 (2) Å. The pyridine ring is essentially coplanar with the central C(= O)N(2)C unit [dihedral angle = 2.02 (3)°] and the phenyl ring exhibits a dihedral angle of 14.41 (10)° with respect to the central unit. The crystal structure features O—H⋯N, N—H⋯O and O—H⋯O hydrogen-bond inter­actions between the solvent water and the benzohydrazide mol­ecules, as well as C—H⋯O hydrogen bonds and C—F⋯π [3.0833 (18) Å] inter­actions. International Union of Crystallography 2012-08-15 /pmc/articles/PMC3435726/ /pubmed/22969597 http://dx.doi.org/10.1107/S1600536812035179 Text en © Nair et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nair, Yamuna
Sithambaresan, M.
Kurup, M. R. Prathapachandra
N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate
title N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate
title_full N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate
title_fullStr N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate
title_full_unstemmed N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate
title_short N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate
title_sort n′-[(e)-(3-fluoro­pyridin-2-yl)methyl­idene]benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435726/
https://www.ncbi.nlm.nih.gov/pubmed/22969597
http://dx.doi.org/10.1107/S1600536812035179
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