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6,6′-Dimethoxy-2,2′-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate
The title compound, C(16)H(16)N(2)O(4)·2CH(3)OH, is a hydrazone in an E geometric arrangement, with an inversion centre at the mid-point of the N—N bond. A symmetry-related pair of six-membered hydrogen-bonded rings [graph-set motif S (1) (1)(6)] are present for the terminal vanillin–imine moieties....
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435728/ https://www.ncbi.nlm.nih.gov/pubmed/22969599 http://dx.doi.org/10.1107/S1600536812034940 |
| _version_ | 1782242578924568576 |
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| author | Randell, Nicholas M. Thompson, Laurence K. Dawe, Louise N. |
| author_facet | Randell, Nicholas M. Thompson, Laurence K. Dawe, Louise N. |
| author_sort | Randell, Nicholas M. |
| collection | PubMed |
| description | The title compound, C(16)H(16)N(2)O(4)·2CH(3)OH, is a hydrazone in an E geometric arrangement, with an inversion centre at the mid-point of the N—N bond. A symmetry-related pair of six-membered hydrogen-bonded rings [graph-set motif S (1) (1)(6)] are present for the terminal vanillin–imine moieties. Two lattice methanol solvent molecules are present per formula unit (Z′ = 1/2), which form hydrogen-bonded chains along [010] with two orientations due to disorder of the methanol H-atom. |
| format | Online Article Text |
| id | pubmed-3435728 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34357282012-09-11 6,6′-Dimethoxy-2,2′-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate Randell, Nicholas M. Thompson, Laurence K. Dawe, Louise N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(16)N(2)O(4)·2CH(3)OH, is a hydrazone in an E geometric arrangement, with an inversion centre at the mid-point of the N—N bond. A symmetry-related pair of six-membered hydrogen-bonded rings [graph-set motif S (1) (1)(6)] are present for the terminal vanillin–imine moieties. Two lattice methanol solvent molecules are present per formula unit (Z′ = 1/2), which form hydrogen-bonded chains along [010] with two orientations due to disorder of the methanol H-atom. International Union of Crystallography 2012-08-15 /pmc/articles/PMC3435728/ /pubmed/22969599 http://dx.doi.org/10.1107/S1600536812034940 Text en © Randell et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Randell, Nicholas M. Thompson, Laurence K. Dawe, Louise N. 6,6′-Dimethoxy-2,2′-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate |
| title | 6,6′-Dimethoxy-2,2′-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate |
| title_full | 6,6′-Dimethoxy-2,2′-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate |
| title_fullStr | 6,6′-Dimethoxy-2,2′-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate |
| title_full_unstemmed | 6,6′-Dimethoxy-2,2′-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate |
| title_short | 6,6′-Dimethoxy-2,2′-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate |
| title_sort | 6,6′-dimethoxy-2,2′-{[(e,e)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435728/ https://www.ncbi.nlm.nih.gov/pubmed/22969599 http://dx.doi.org/10.1107/S1600536812034940 |
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