Cargando…

(E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium 4-meth­oxy­benzene­sulfonate monohydrate

In the cation of the title compound, C(18)H(23)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, one ethyl group of the diethyl­amino unit is disordered over two sets of sites in a 0.665 (6):0.335 (6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of...

Descripción completa

Detalles Bibliográficos
Autores principales: Chantrapromma, Suchada, Kaewmanee, Narissara, Boonnak, Nawong, Anantapong, Teerasak, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435741/
https://www.ncbi.nlm.nih.gov/pubmed/22969612
http://dx.doi.org/10.1107/S1600536812035258
Descripción
Sumario:In the cation of the title compound, C(18)H(23)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, one ethyl group of the diethyl­amino unit is disordered over two sets of sites in a 0.665 (6):0.335 (6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of 4.27 (8)°. In the crystal, the anion ring is almost perpendicular to the aromatic rings of the cation; the sulfonate-substituted benzene ring forms dihedral angles of 89.60 (8) and 89.37 (8)°, respectively, with the pyridinium and benzene rings of the cation. In the crystal, the three components are linked into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds. π–π inter­actions with centroid–centroid distances of 3.6999 (9) and 3.7106 (9) Å are also present.